Examining the Effects of Neem Leaf Extract Additive on Biodiesel Blends for Improved Fuel Efficiency and Engine Performance in a Low Heat Rejection Engine
J. Environ. Nanotechnol., Volume 14, No 1 (2025) pp. 543-557
Abstract
This research assessed the performance, combustion behavior, and emission characteristics of three biodiesel sources—Pongamia pinnata, Juliflora, and Calophyllum inophyllum—blended with conventional diesel in a low heat rejection (LHR) engine. It also examined the impact of neem leaf extract as an additive. B20 blends (20% biodiesel, 80% diesel) were formulated and tested under different load conditions in a single-cylinder diesel engine, where key components were coated with partially stabilized zirconia. The neem leaf extract concentration was varied using a central composite design to evaluate its effects. Essential fuel properties, including oxidation stability, viscosity, cetane number, and flash point, were analyzed. The study also investigated combustion parameters such as brake thermal efficiency, fuel consumption, exhaust gas temperature, cylinder pressure, heat release rate, and ignition delay, alongside CO, HC, NOx, and particulate matter emissions. Results indicated that biodiesel blends exhibited superior brake thermal efficiency compared to pure diesel, particularly at higher loads, with Pongamia pinnata biodiesel showing the best performance. Adding 2.5% neem leaf extract further improved efficiency across all blends. Biodiesel blends led to lower CO, HC, and particulate emissions but caused a slight increase in NOx emissions due to elevated combustion temperatures. However, neem leaf extract helped counteract the rise of NOx. Higher cylinder pressures and heat release rates were observed with biodiesel blends, indicating enhanced combustion, while ignition delays were reduced, with neem extract further minimizing them. The findings highlight the potential of these biodiesel feedstocks as sustainable diesel alternatives, with neem leaf extract serving as a natural additive to enhance fuel properties, combustion efficiency, and emissions control in LHR engines.
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Reference
Agrawal, P., Gnanaprakash, R. and Dhawane, S. H., Prediction of Biodiesel Yield Employing Machine Learning: Interpretability Analysis via Shapley Additive Explanations, Fuel, 359, 130516(2024).
https://doi.org/10.1016/j.fuel.2023.130516
Arun, S. B., Karthik, B. M., Yatish, K. V., Prashanth, K. N. and Balakrishna, G. R., Green synthesis of copper oxide nanoparticles using the Bombax ceiba plant: Biodiesel production and nano-additive to investigate diesel engine performance-emission characteristics, Energy, 274, 127345(2023).
https://doi.org/10.1016/j.energy.2023.127345
Arunraj, R. and Amala, J. S. M., An Experimental Study on Algae Biodiesel with Nano-additives for Engine Performance and Emission Reduction, J. Environ. Nanotechnol., 13(3), 361–373 (2024).
https://doi.org/10.13074/jent.2024.09.242678
Baradhsundar, V. S. and Srinivaas, A., Simulation Study on the Influence of the Traffic Conditions on Vehicle Performance and Emission, J. Environ. Nanotechnol., 13(2), 88–97 (2024).
https://doi.org/10.13074/jent.2024.06.241527
Cui, L., Chen, J., Xu, B., Chen, Y., Pan, Y., Lin, H. and Sheng, H., Effects of purified Ginkgo biloba L. leaf extract on the oxidative stability and cold flow properties of biodiesel-diesel blends, Ind. Crops Prod., 212, 118277(2024).
https://doi.org/10.1016/j.indcrop.2024.118277
Devi, A., Das, V. K. and Deka, D. A., green approach for enhancing oxidation stability including long storage periods of biodiesel via Thuja oreantalis L. as an antioxidant additive, Fuel, 253, 1264–73(2019).
https://doi.org/10.1016/j.fuel.2019.05.127
Doğan, B., Yeşilyurt, M. K., Yaman, H., Korkmaz, N. and Arslan, A., Green synthesis of SiO2 and TiO2 nanoparticles using safflower (Carthamus tinctorius L.) leaves and investigation of their usability as alternative fuel additives for diesel-safflower oil biodiesel blends, Fuel, 367, 131498(2024).
https://doi.org/10.1016/j.fuel.2024.131498
Fernandes, F. D., Ferreira, L. M. and Silva, M. L. C. P., Application of Psidium guajava L. leaf extract as a green corrosion inhibitor in biodiesel: Biofilm formation and encrustation, Appl. Surf. Sci. Adv., 6, 100185(2021).
https://doi.org/10.1016/j.apsadv.2021.100185
Fernandes, F. D., Ferreira, L. M. and Silva, M. L. C. P., Evaluation of the corrosion inhibitory effect of the eco-friendly additive of Terminalia Catappa leaf extract added to soybean oil biodiesel in contact with zinc and carbon steel 1020, J. Clean Prod., 321, 128863(2021).
https://doi.org/10.1016/j.jclepro.2021.128863
França, F. R. M., Santos, F. D. L., Ramos, A. L. D., Silva, G. F. and Brandão, S. T., Storage and oxidation stability of commercial biodiesel using Moringa oleifera Lam as an antioxidant additive, Fuel, 203, 627–32(2017).
https://doi.org/10.1016/j.fuel.2017.03.020
Gaur, A., Dwivedi, G., Baredar, P. and Jain, S., Influence of blending additives in biodiesel on physiochemical properties, engine performance, and emission characteristics, Fuel, 321, 124072(2022).
https://doi.org/10.1016/j.fuel.2022.124072
Jain, S., Purohit, S., Kumar, D. and Goud, V. V., Passion fruit seed extract as an antioxidant additive for biodiesel; shelf life and consumption kinetics, Fuel, 289, 119906(2021).
https://doi.org/10.1016/j.fuel.2020.119906
Jeyakumar, N., Narayanasamy, B., Balasubramanian, D. and Viswanathan, K., Characterization and effect of Moringa oleifera Lam. antioxidant additive on the storage stability of Jatropha biodiesel, Fuel, 281,118614(2020).
https://doi.org/10.1016/j.fuel.2020.118614
Karunanithi, G. and Varadappan, A. M. S., Exploring the effectiveness of novel Coffea Arabica leaf pigment as a natural antioxidant additive for date seed biodiesel, Fuel, 324, 124561 (2022).
https://doi.org/10.1016/j.fuel.2022.124561
Lau, C. H., Gan, S., Lau, H. L. N., Lee, L. Y., Thangalazhy, G. S. and Ng, H. K., Insights into the effectiveness of synthetic and natural additives in improving biodiesel oxidation stability, Sustainable Energy Technol. Assess., 52, 102296 (2022).
https://doi.org/10.1016/j.seta.2022.102296
Lim, H. Y., Tang, S. H., Chai, Y. H., Yusup, S., Lim, M. T., Co-pyrolysis of plastics and food waste mixture under flue gas condition for bio-oil production, Sustainable Energy Technol. Assess., 54, 102826 (2022).
https://doi.org/10.1016/J.SETA.2022.102826
Maárof, M. I. N., Chala, G. T., Gunness, D. and Saad, I., A study on the performance analysis of bioethanol produced from sugarcane molasses in SI engine, IOP Conf. Ser. Mater. Sci. Eng., 863, 012064(2020).
https://doi.org/10.1088/1757-899X/863/1/012064
Manimaran, R., Mohanraj, T. and Ashwin, R., Green synthesized nano-additive dosed biodiesel-diesel-water emulsion blends for CI engine application: Performance, combustion, emission, and exergy analysis, J. Clean Prod., 413, 137497(2023).
https://doi.org/10.1016/j.jclepro.2023.137497
Nambiraj, M. and Suresh, K. K., Exploring the role of natural antioxidant additives extracted from agro wastes in prolonging biodiesel’s storage stability, Ind. Crops Prod., 212, 118321(2024).
https://doi.org/10.1016/j.indcrop.2024.118321
Rial, R. C., Merlo, T. C., Michalski, S. P. H., Dias, M. L. F., Barbosa, R. A., Freitas, O. N., Carlos, E. D. N. and Viana, L. H., Evaluation of oxidative stability of soybean methyl biodiesel using extract of cagaite leaves (Eugenia dysenterica DC.) as additive, Renew. Energy, 152, 1079–85(2020).
https://doi.org/10.1016/j.renene.2020.01.121
Sannagoudar, B. A., Maleki, B., Prakash, R. M., Mounesh, K. P., Kalanakoppal, V. Y., Exploitation of Annona reticulata leaf extract for the synthesis of CeO2 nanoparticles as catalyst for the production of biodiesel using seed oil thereof, Energy, 298, 131335(2024).
https://doi.org/10.1016/j.energy.2024.131335
Shelare, S. D., Belkhode, P. N., Nikam, K. C., Jathar, L. D., Shahapurkar, K., Soudagar, M. E. M., Veza, I., Khan, T. M. Y., Kalam, M. A., Nizami, A. S. and Rehan, M., Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production, Energy, 282, 128874(2023).
https://doi.org/10.1016/j.energy.2023.128874
Viswanathan, K., Ashok, B. and Pugazhendhi, A., Comprehensive study of engine characteristics of novel biodiesel from curry leaf (Murraya koenigii) oil in ceramic layered diesel engine, Fuel, 280,118586(2020).
https://doi.org/10.1016/j.fuel.2020.118586
Zeleke, D. S. and Bezabih, A. A., Impact of additives from moringa stenopetela leaf extract and ethanol on the emission characteristics and performance of soybean biodiesel for single cylinder CI engine, Heliyon 10(6), e27619(2024).