Open Access

Exploring the Impact of Titanium Dioxide Nanoparticles as Fuel Additives in Candlenut Biodiesel–diesel Blends in a CI Engine

G. Antony Casmir Jayaseelan, Department of Mechanical Engineering, Aarupadai Veedu Institute of Technology, Vinayaka Mission's Research Foundation, Chennai, TN, India B. Musthafa, avsmus@gmail.com
Department of Mechanical Engineering, Aarupadai Veedu Institute of Technology, Vinayaka Mission's Research Foundation, Chennai, TN, India
A. Anderson, Department of Mechanical Engineering, Sathyabama Institute of Science and Technology, Chennai, TN, India J. Antony Abishek, Department of Mechanical Engineering, Aarupadai Veedu Institute of Technology, Vinayaka Mission's Research Foundation, Chennai, TN, India K. Bhuvaneshwaran Department of Mechanical Engineering, Aarupadai Veedu Institute of Technology, Vinayaka Mission's Research Foundation, Chennai, TN, India


J. Environ. Nanotechnol., Volume 14, No 1 (2025) pp. 84-90

https://doi.org/10.13074/jent.2025.03.2511244

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Abstract

Candlenut, a renewable biodiesel synthesized via transesterification, offers a sustainable alternative to fossil-based diesel. This study aims to produce candlenuts using a transesterification method with methanol as a catalyst. Candlenut was blended with conventional diesel in varying volumetric proportions of B20, B40, and B60 to assess its viability as an alternative fuel. Furthermore, ultrasonic dispersion was used to incorporate TiO2 nanoparticles into the biodiesel blends to enhance fuel properties, and the physicochemical characteristics of the nanoadditive-enriched fuel blends were systematically analyzed. A comprehensive experimental evaluation of combustion, performance, and emission parameters was conducted on a single-cylinder diesel engine using these modified fuel blends, with baseline diesel operation as the reference. The findings indicate that the B20 biodiesel blend, which has been added with TiO2 nanoparticles, shows superior combustion characteristics, improved performance, and emission characteristics in comparison to conventional diesel.

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Reference


Abed, K. A., Gad, M. S., Morsi, A. K., Sayed, M. M., Elyazeed, S. A., Effect of biodiesel fuels on diesel engine emissions, Egypt. J. Pet., 28(2), 183–188 (2019).

https://doi.org/10.1016/j.ejpe.2019.03.001

Anil, B. K., Ramana, S. V., Hadya, B. and Subramani, S., Investigation on NOx control of a CI engine through the collective effect of hydrogen and biodiesel blend at modified compression ratio, Int. J. Hydrogen Energy, 82, 624–635(2024).

https://doi.org/10.1016/j.ijhydene.2024.07.337

Antony, C. J. G., Anderson, A., Manigandan, S., Elfasakhany, A. and Dhinakaran, V., Effect of engine parameters, combustion and emission characteristics of diesel engine with dual fuel operation, Fuel, 302, 121152(2021).

https://doi.org/10.1016/j.fuel.2021.121152

Ashwarya, S., Emerging Contours of India–US Fossil Fuel Trade, Strateg. Anal., 44(4), 312–331(2020).

https://doi.org/10.1080/09700161.2020.1809203

Baskar, G., Kalavathy, G., Aiswarya, R. and Abarnaebenezer, S., 7 - Advances in bio-oil extraction from nonedible oil seeds and algal biomass, Adv. Eco-Fuels Sustainable Environ., 187–210 (2019).

https://doi.org/10.1016/B978-0-08-102728-8.00007-3

Chivu, R. M., Martins, J., Popescu, F., Uzuneanu, K., Ion, I. V., Goncalves, M., Codău, T. C., Onofrei, E. and Brito, F. P., Turpentine as an Additive for Diesel Engines: Experimental Study on Pollutant Emissions and Engine Performance, Energies, 16(13), 5150 (2023).

https://doi.org/10.3390/en16135150

Dhairiyasamy, R. and Murugesan, E., Reducing NOx emissions in biodiesel-powered LHR engines using an antioxidant additive: a methodological approach, Int. J. Ambient Energy, 45(1), 2279139(2024).

https://doi.org/10.1080/01430750.2023.2279139

Dubey, P. and Gupta, R., Influences of dual bio-fuel (Jatropha biodiesel and turpentine oil) on single cylinder variable compression ratio diesel engine, Renew. Energy, 115, 1294–1302(2018).

https://doi.org/10.1016/j.renene.2017.09.055

Esakki, T., Rangaswamy, S. M. and Jayabal, R., An experimental study on biodiesel production and impact of EGR in a CRDI diesel engine propelled with leather industry waste fat biodiesel, Fuel, 321, 123995(2022).

https://doi.org/10.1016/j.fuel.2022.123995

Fayad, M. A., Sobhi, M., Chaichan, M. T., Tawfik, B., Wiswam, E. A. L., Hayder, A. D., Talai, Y., Isahak, W. N. R. W., Takriff, M. S. and Ahmed, A. A., Reducing Soot Nanoparticles and NOX Emissions in CRDI Diesel Engine by Incorporating TiO2 Nano-Additives into Biodiesel Blends and Using High Rate of EGR, Energies, 16(9), 3921(2023).

https://doi.org/10.3390/en16093921

Huang, Y., Fu, J., Xia, A., Zhu, X., Zhu, X. and Liao, Q., Step-wise SO2-feeding strategies for microalgae-based CO2 fixation from flue gas and bioenergy production, Chem. Eng. J., 468, 143646(2023).

https://doi.org/10.1016/j.cej.2023.143646

Jit, S. C., Sharma, P., Bora, B. J.,Bora, D. K., Natarajan, S., Deepanraj, B. and Ayesh, I. A., Improving the combustion and emission performance of a diesel engine powered with mahua biodiesel and TiO2 nanoparticles additive, Alexandria Eng. J., 72, 387–398(2023).

https://doi.org/10.1016/j.aej.2023.03.070

Makepa, D. C., Fumhirwa, D. V., Tambula, S. and Chihobo, C. H., Performance analysis, techno-economic and life cycle assessment of Jatropha curcas L. (Euphorbiaceae) seedcake gasification and Fischer-Tropsch integrated process for bio-methanol production, Biofuels, 15(1), 57–66(2024).

https://doi.org/10.1080/17597269.2023.2216957

Musthafa, B. and Asokan, M. A., Impact of Fuel Hydrogenation and Fuel Additives on Dual Biodiesel Mixture for Improving Combustion and Emission Characteristics in Compression Ignition Engine, Solid Fuel Chem., 57(7), 481–493(2023).

https://doi.org/10.3103/S0361521923080050

Rezania, S., Mahdinia, S., Oryani, B., Cho, J. Kwan, E. E., Alireza, B., Hamid, R. N., Negisa, D. and Kamyar, M., Biodiesel production from wild mustard (Sinapis Arvensis) seed oil using a novel heterogeneous catalyst of LaTiO3 nanoparticles, Fuel, 307, 121759 (2022).

https://doi.org/10.1016/j.fuel.2021.121759

Rozina, Chia, S. R., Ahmad, M., Shazia, S., Zafar, M., Asif, S., Bokhari, A., Nomanbhay, S., Mubashir, M., Kuan, S. K. and Pau, L. S., Green synthesis of biodiesel from Citrus medica seed oil using green nanoparticles of copper oxide, Fuel, 323, 124285 (2022).

https://doi.org/10.1016/j.fuel.2022.124285

Saravanan, A., Murugan, M., Sreenivasa, R. M. and Parida, S., Performance and emission characteristics of variable compression ratio CI engine fueled with dual biodiesel blends of Rapeseed and Mahua, Fuel, 263, 116751(2020).

https://doi.org/10.1016/j.fuel.2019.116751

Sateesh, K. A., Yaliwal, V. S., Soudagar, M. E., et al., Utilization of biodiesel/Al2O3 nanoparticles for combustion behavior enhancement of a diesel engine operated on dual fuel mode, J. Therm. Anal. Calorim., 147(10), 5897-5911 (2022).

https://doi.org/10.1007/s10973-021-10928-7

Sayyed, S., Das, R. K. and Kulkarni, K., Experimental investigation for evaluating the performance and emission characteristics of DICI engine fueled with dual biodiesel-diesel blends of Jatropha, Karanja, Mahua, and Neem, Energy, 238, 121787(2022).

https://doi.org/10.1016/j.energy.2021.121787

Shaah, M. A., Allafi, F., Hossain, M. S., Alyaa, A., Ismail, N., Kadir, M. O. A. and Ahmad, M. I., Candlenut oil: review on oil properties and future liquid biofuel prospects, Int. J. Energy Res., 45(12), 17057–17079 (2021).

https://doi.org/10.1002/er.6446

Venkataramana, S. and Ramanaiah, N., Analysis of an Emission and Performance Characteristics of Single Cylinder 4 Stroke VCR Engine by Using Palm Biodiesel Blends and Comparison at the Compression Ratio 18:1, Recent Trends Prod. Des Intell. Manuf. Syst., 545–554(2023).

https://doi.org/10.1007/978-981-19-4606-6_50

Verma, S., Upadhyay, R., Shankar, R. and Pandey, S. P., Performance and emission characteristics of micro-algae biodiesel with butanol and TiO2 nano-additive over diesel engine, Sustain. Energy Technol. Assessments, 55, 102975(2023).

https://doi.org/10.1016/j.seta.2022.102975

Wei, Y., Liu, J., Lai, X. and Hu, Y., Which determinant is the most informative in forecasting crude oil market volatility: Fundamental, speculation, or uncertainty?, Energy Econ., 68, 141–150(2017).

https://doi.org/10.1016/j.eneco.2017.09.016

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