Open Access

Influence of Nano-SiO₂ and Nano-TiO₂ on Self-Compacting Concrete: A Study of Rheology and Strength Improvement

E. Kavitha, kavi13suga@gamil.com
Department of Civil Engineering, Aishwarya College of Engineering and Technology, Bhavani, TN, India
S. Revathi, Department of Civil Engineering, Mahendra Engineering College, Namakkal, TN, India L. Reena, Department of Civil Engineering, Builders Engineering College, Kangeyam, TN, India C. Vinodhini Department of Civil Engineering, KPR Institute of Engineering and Technology, Arasur, Coimbatore, TN, India


J. Environ. Nanotechnol., Volume 13, No 4 (2024) pp. 161-168

https://doi.org/10.13074/jent.2024.12.2441074

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Abstract

Self-Compacting Concrete (SCC), known as advanced concrete, flows and consolidates under its own weight, even in confined or congested spaces, without mechanical vibration. This study examines the impact of using nanoparticles, namely Nano-Silica (N-SiO₂) and Nano-Titanium Dioxide (N-TiO₂), as a partial replacement for cement in SCC. Six mix variations were created with different quantities of N-SiO₂ and N-TiO₂, and their fresh and hardened characteristics were tested. Fresh-state tests, such as slump flow, V-funnel, and L-box, proved the good workability and passing ability of all mixtures, which met EFNARC 2005 requirements. The combination of 6% N-SiO₂ and 4% N-TiO₂ performed best in terms of mechanical strength. SEM studies demonstrated that the optimized mix had better particle packing, fewer voids, and a greater density. Water absorption tests revealed enhanced durability and lower permeability. The findings indicated that the use of nanoparticles enhances the flowability, strength, and durability of nano-modified SCC.

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Reference


Althoey, F., Zaid, O., Martínez-García, R., Alsharari, F., Ahmed, M. and Arbili, M. M., Impact of Nano-silica on the hydration, strength, durability, and microstructural properties of concrete: A state-of-the-art review, Case Stud. Constr. Mater., 18, e01997 (2023).

https://doi.org/10.1016/j.cscm.2023.e01997

Chen, J. and Poon, C. S., Photocatalytic activity of titanium dioxide modified concrete materials – Influence of utilizing recycled glass cullets as aggregates, J. Environ. Manage., 90(11), 3436–3442 (2009). https://doi.org/10.1016/j.jenvman.2009.05.029

Chinthakunta, R., Ravella, D. P., Sri Rama Chand, M. and Janardhan Yadav, M., Performance evaluation of self-compacting concrete containing fly ash, silica fume and nano titanium oxide, Mater. Today Proc., 43, 2348–2354 (2021).

https://doi.org/10.1016/j.matpr.2021.01.681

Chithra, S., Senthil Kumar, S. R. R. and Chinnaraju, K., The effect of Colloidal Nano-silica on workability, mechanical and durability properties of High Performance Concrete with Copper slag as partial fine aggregate, Constr. Build. Mater., 113, 794–804 (2016).

https://doi.org/10.1016/j.conbuildmat.2016.03.119

Furumura, T., Tokushige, H. and Kawakami, M., Physical Properties and NOx Remediation of Cement Mortar Incorporating Titanium Dioxide Powder, J. Soc. Mater. Sci. Japan, 55(10), 923–928 (2006).

https://doi.org/10.2472/jsms.55.923

Ghafari, E., Costa, H., Júlio, E., Portugal, A. and Durães, L., The effect of nanosilica addition on flowability, strength and transport properties of ultra high performance concrete, Mater. Des., 59, 1–9 (2014).

https://doi.org/10.1016/j.matdes.2014.02.051

Hanus, M. J. and Harris, A. T., Nanotechnology innovations for the construction industry, Prog. Mater. Sci., 58(7), 1056–1102 (2013).

https://doi.org/10.1016/j.pmatsci.2013.04.001

Hossain, K. M. A. and Lachemi, M., Fresh, Mechanical, and Durability Characteristics of Self-Consolidating Concrete Incorporating Volcanic Ash, J. Mater. Civ. Eng., 22(7), 651–657 (2010).

https://doi.org/10.1061/(ASCE)MT.1943-5533.0000063

Ichiura, H., Kitaoka, T. and Tanaka, H., Removal of indoor pollutants under UV irradiation by a composite TiO2–zeolite sheet prepared using a papermaking technique, Chemosphere, 50(1), 79–83 (2003).

https://doi.org/10.1016/S0045-6535(02)00604-5

Jalal, M., Fathi, M. and Farzad, M., RETRACTED: Effects of fly ash and TiO2 nanoparticles on rheological, mechanical, microstructural and thermal properties of high strength self compacting concrete, Mech. Mater., 61, 11–27 (2013).

https://doi.org/10.1016/j.mechmat.2013.01.010

Joshaghani, A., Balapour, M., Mashhadian, M. and Ozbakkaloglu, T., Effects of nano-TiO2, nano-Al2O3, and nano-Fe2O3 on rheology, mechanical and durability properties of self-consolidating concrete (SCC): An experimental study, Constr. Build. Mater., 245, 118444 (2020).

https://doi.org/10.1016/j.conbuildmat.2020.118444

Kumar, S., Kumar, A. and Kujur, J., Influence of nanosilica on mechanical and durability properties of concrete, Proc. Inst. Civ. Eng. - Struct. Build., 172(11), 781–788 (2019).

https://doi.org/10.1680/jstbu.18.00080

Li, H., Zhang, M. and Ou, J., Abrasion resistance of concrete containing nano-particles for pavement, Wear, 260(11–12), 1262–1266 (2006).

https://doi.org/10.1016/j.wear.2005.08.006

Maggos, T., Plassais, A., Bartzis, J. G., Vasilakos, C., Moussiopoulos, N. and Bonafous, L., Photocatalytic degradation of NOx in a pilot street canyon configuration using TiO2-mortar panels, Environ. Monit. Assess., 136(1–3), 35–44 (2007).

https://doi.org/10.1007/s10661-007-9722-2

Massana, J., Reyes, E., Bernal, J., León, N. and Sánchez-Espinosa, E., Influence of nano- and micro-silica additions on the durability of a high-performance self-compacting concrete, Constr. Build. Mater., 165, 93–103 (2018).

https://doi.org/10.1016/j.conbuildmat.2017.12.100

Mohseni, E., Miyandehi, B. M., Yang, J. and Yazdi, M. A., Single and combined effects of nano-SiO2, nano-Al2O3 and nano-TiO2 on the mechanical, rheological and durability properties of self-compacting mortar containing fly ash, Constr. Build. Mater., 84, 331–340 (2015).

https://doi.org/10.1016/j.conbuildmat.2015.03.006

Mosaberpanah, M. A. and Umar, S. A., Utilizing Rice Husk Ash as Supplement to Cementitious Materials on Performance of Ultra High Performance Concrete: – A review, Mater. Today Sustain., 7–8, 100030 (2020).

https://doi.org/10.1016/j.mtsust.2019.100030

Nazari, A. and Riahi, S., The effect of TiO2 nanoparticles on water permeability and thermal and mechanical properties of high strength self-compacting concrete, Mater. Sci. Eng. A, 528(2), 756–763 (2010).

https://doi.org/10.1016/j.msea.2010.09.074

Nazari, A. and Riahi, S., The role of SiO2 nanoparticles and ground granulated blast furnace slag admixtures on physical, thermal and mechanical properties of self compacting concrete, Mater. Sci. Eng. A, 528(4–5), 2149–2157 (2011).

https://doi.org/10.1016/j.msea.2010.11.064

Paz, Y., Luo, Z., Rabenberg, L. and Heller, A., Photooxidative self-cleaning transparent titanium dioxide films on glass, J. Mater. Res., 10(11), 2842–2848 (1995).

https://doi.org/10.1557/JMR.1995.2842

Praveen, K. V. V. and Dey, S., Study on strength and durability characteristics of nano-silica based blended concrete, Hybrid Adv., 2, 100011 (2023).

https://doi.org/10.1016/j.hybadv.2022.100011

Rawat, G., Gandhi, S. and Murthy, Y. I., Strength and rheological aspects of concrete containing nano-titanium dioxide, Asian J. Civ. Eng., 23(8), 1197–1208 (2022).

https://doi.org/10.1007/s42107-022-00476-2

Riahi, S. and Nazari, A., RETRACTED ARTICLE: Compressive strength and abrasion resistance of concrete containing SiO2 and CuO nanoparticles in different curing media, Sci. China Technol. Sci., 54(9), 2349–2357 (2011). https://doi.org/10.1007/s11431-011-4463-4

Safiuddin, M., West, J. S. and Soudki, K. A., Air content of self-consolidating concrete and its mortar phase including rice husk ash / oro kiekis savitankiame betone ir jo skiedinio dalyje su ryžių lukštų pelenais, J. Civ. Eng. Manag., 17(3), 319–329 (2011).

https://doi.org/10.3846/13923730.2011.589225

Sanchez, F. and Sobolev, K., Nanotechnology in concrete – A review, Constr. Build. Mater., 24(11), 2060–2071 (2010).

https://doi.org/10.1016/j.conbuildmat.2010.03.014

Singh, L. P., Ali, D., Tyagi, I., Sharma, U., Singh, R. and Hou, P., Durability studies of nano-engineered fly ash concrete, Constr. Build. Mater., 194, 205–215 (2019).

https://doi.org/10.1016/j.conbuildmat.2018.11.022

Singh, L. P., Karade, S. R., Bhattacharyya, S. K., Yousuf, M. M. and Ahalawat, S., Beneficial role of nanosilica in cement based materials – A review, Constr. Build. Mater., 47, 1069–1077 (2013).

https://doi.org/10.1016/j.conbuildmat.2013.05.052

Uysal, M. and Yilmaz, K., Effect of mineral admixtures on properties of self-compacting concrete, Cem. Concr. Compos., 33(7), 771–776 (2011).

https://doi.org/10.1016/j.cemconcomp.2011.04.005

Varghese, L., Rao, V. V. L. K. and Parameswaran, L., Nanosilica-added concrete: strength and its correlation with time-dependent properties, Proc. Inst. Civ. Eng. - Constr. Mater., 172(2), 85–94 (2019).

https://doi.org/10.1680/jcoma.17.00031

Vejmelková, E., Keppert, M., Grzeszczyk, S., Skaliński, B. and Černý, R., Properties of self-compacting concrete mixtures containing metakaolin and blast furnace slag, Constr. Build. Mater. 25(3), 1325–1331 (2011).

https://doi.org/10.1016/j.conbuildmat.2010.09.012

Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M. and Watanabe, T., Photogeneration of Highly Amphiphilic TiO2 Surfaces, Adv. Mater., 10(2), 135–138 (1998).

https://doi.org/10.1002/(SICI)1521-4095(199801)10:2<135::AID-ADMA135>3.0.CO;2-M

Yang, L. Y., Jia, Z. J., Zhang, Y. M. and Dai, J. G., Effects of nano-TiO2 on strength, shrinkage and microstructure of alkali activated slag pastes, Cem. Concr. Compos., 57, 1–7 (2015).

https://doi.org/10.1016/j.cemconcomp.2014.11.009

Yuranova, T., Sarria, V., Jardim, W., Rengifo, J., Pulgarin, C., Trabesinger, G. and Kiwi, J., Photocatalytic discoloration of organic compounds on outdoor building cement panels modified by photoactive coatings, J. Photochem. Photobiol. A Chem., 188(2–3), 334–341 (2007).

https://doi.org/10.1016/j.jphotochem.2006.12.032

Zhang, M. and Li, H., Pore structure and chloride permeability of concrete containing nano-particles for pavement, Constr. Build. Mater., 25(2), 608–616 (2011).

https://doi.org/10.1016/j.conbuildmat.2010.07.032

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