Open Access

Green Route Synthesis of Fe3O4 Nanoparticles and Exploring its Photochemical Activity and Antibacterial Activity

J. Manikandan, manikandan@psgcas.ac.in
1Department of Chemistry, PSG College of Arts & Science, Coimbatore, TN, India
P. Rajesh, Department of Chemistry, Government Arts College, Coimbatore, TN, India S.V.K. Selvakumar Department of Chemistry, Government Arts College, Coimbatore, TN, India


J. Environ. Nanotechnol., Volume 11, No 1 (2022) pp. 01-05

https://doi.org/10.13074/jent.2022.03.221448

PDF


Abstract

Green synthesis of magnetite nanoparticles is a significantly developing methodology because of its biocompatibility. In the present work, iron oxide nanoparticles (IONPs) were synthesized by a simple Co-precipitation method using Commiphora berryi plant exudates. FTIR, XRD and SEM techniques were used to characterize the as-synthesised iron oxide nanoparticles. Photocatalytic activity of synthesized iron oxide nanoparticles was determined against Methylene blue (MB) dye in an aqueous medium. Iron oxide nanoparticles acted as a photocatalyst and decomposed the dye under solar irradiation. Results show that 73 % of degradation efficiency was attained after 150 minutes with a nanoparticle dosage of 0.5 mg/L, making the IONPs a potential applicant for various effluent treatment methods. Further, the results indicate that the efficiency increases with increasing pH and decreases with increasing MB dye concentration. The antimicrobial activity of IONPS has been studied against Escherichia coli and Staphylococcus aureus. IONPs show excellent antibacterial activity for both the organisms with 16.5 mm and 16.75 mm zone of inhibition, for E. coli and S. aureus , respectively.   

Full Text

Reference


Adrian Radon, Patryk Włodarczyk, Aleksandra Drygała and Dariusz Łukowiec, Electrical properties of epoxy nanocomposites containing Fe3O4 nanoparticles and Fe3O4 nanoparticles deposited on the surface of electrochemically exfoliated and oxidized graphite, Appl. Surf. Sci., 474, 66-77 (2019).

https://doi.org/10.1016/j.apsusc.2018.05.045

Arsalani, S., Guidelli, E. J., Araujo, F.D.F., Bruno, A.C., Baffa, O., Green Synthesis and Surface Modification of Iron Oxide Nanoparticles with Enhanced Magnetization Using Natural Rubber Latex, ACS Sustainable Chem. Eng., 6 (11), 13756-13765 (2018).

https://doi.org/10.1021/acssuschemeng.8b01689

Fahad, M., and Alminderej, Study of new cellulosic dressing with enhanced antibacterial performance grafted with a biopolymer of chitosan and myrrh polysaccharide extract., Arabian J. Chem., 13, 3672-3681 (2020).

https://doi.org/10.1016/j.arabjc.2019.12.005

Ghosh, M., Manoli, K., Shen, X., Wang, J., and Ray, A.K., Solar photocatalytic degradation of caffeine with titanium dioxide and zinc oxide nanoparticles, J. Photochem. Photobiol. A: Chem., (377), 1-7 (2019).

https://doi.org/10.1016/j.jphotochem.2019.03.029

Islam, M. A., Ali, I., Karim, S. M. A., Hossain and Firoz M. S, A.-N. Chowdhury, D.W. Morton and M.J. Angove, Removal of dye from polluted water using novel nano manganese oxidebased materials, J. Water Process Eng., (32), 100911-100918 (2019).

https://doi.org/10.1016/j.jwpe.2019.100911

Junwang, Tang, Zhigang, Zou, and Jinhue, Ye, Kinetics of MB degradation and effect of pH on the photocatalytic activity of MIn2O4 (M=Ca, Sr, Ba) under visible light irradiation, Res. Chem. Intermed., 31, 513-519 (2005).

https://doi.org/10.1163/1568567053956699

Latha, S., Selvamani, P., Pal, T. K., Gupta, J. K., and Ghosh, L. K., Pharmacognostical studies on leaves of Commiphora caudata (Wight & Arn) engl, Ancient Sci. Life, XXVI (1&2), 19-25 (2006).

Mahdavi, Mahnaz, Mansor Bin Ahmad, Md Jelas Haron, Farideh Namvar, Behzad Nadi, Mohamad Zaki Ab Rahman and Jamileh Amin, Synthesis, Surface Modification and Characterisation of Biocompatible Magnetic Iron Oxide Nanoparticles for Biomedical Applications, Molecules, 18, 7533-7548, (2013).

https://doi.org/10.3390/molecules18077533

Mohapatra, M. and Anand, S., Synthesis and applications of nano-structured iron oxides/hydroxides-a review, Int. J. Eng. Sci. Technol, 2(8), 127-146 (2010).

https://doi.org/10.4314/ijest.v2i8.63846

Motahari, F., Mozdianfard, M. R., Soofivand, F., and M. SalavatiNiasari, NiO nanostructures: synthesis, characterization and photocatalyst application in dye wastewater treatment, RSC Adv, 4, 27654–27660, (2014).

https://doi.org/10.1039/C4RA02697G

Nwankwo, U., Bucher, R., Ekwealor, A.B.C, Khamlich, S., Maaza, M. and Ezema, F.I., Synthesis and characterizations of rutile-TiO2 nanoparticles derived from chitin for potential photocatalytic applications, Vacuum, 161, 49–54 (2019).

https://doi.org/10.1016/j.egyr.2020.02.010

Shi, R., Chen, G., Ma, W., Zhang, D., Qiu, G. and Liu, X., Shape-controlled synthesis and characterization of cobalt oxides hollow spheres and octahedral, Dalton Trans, 41, 5981-5987 (2012).

https://doi.org/10.1039/C2DT12403C

Suman, T. Y., Elumalai, D., Kaleena, P.K. and Radhika, Rajasree, S., GC–MS analysis of bioactivecomponents and synthesis of silver nanoparticle using Ammannia accifera aerial extract and its larvicidal activity against malaria and filariasis vectors, Ind. Crops., Prod, 47, 239-245 (2013).

https://doi.org/10.1016/j.indcrop.2013.03.010

Tania, Tofaz., Dhananjoy Chandra Mahanto, Shamima Akhter, Md. Mahbubor Rahman, M. Abdul Latif, Synthesis and Characterization of Bi-Functional Poly (Acrylic Acid-Co-2-hydroxyethylmethacrylate) Coated Iron Oxide Magnetic Composite Particles, American J. Polymer Sci. Technol., 5(1), 1-8 (2019).

https://doi.org/10.11648/j.ajpst.20190501.11

Zahir, A. A. and Rahuman A. A., Evaluation of different extracts and synthesised silver nanoparticles from leaves of Euphorbia prostrata against Haemaphysalis bispinosa and Hippobosca maculate, Vet. Parasitol., 187, 511-520 (2012).

https://doi.org/10.1016/j.vetpar.2012.02.001

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS