Open Access

Synthesis of Multi-walled Carbon Nanotubes from Glycine Max Oil and Their Potential Applications

V.S. Angulakshmi, Department of Chemistry, Kathir College of Engineering, Coimbatore, TN, India C. Sathiskumar, Department of Chemistry Chickkanna Government Arts College, Tirupur, TN, India S. Karthikeyan skmush@yahoo.co.in
Department of Chemistry Chickkanna Government Arts College, Tirupur, TN, India


J. Environ. Nanotechnol., Volume 2, No (Special Issue) (2013) pp. 101-106

https://doi.org/10.13074/jent.2013.02.nciset316

PDF


Abstract

The discovery of carbon nanotubes has created new era in the field of nanotechnology. Spectacular properties of these nanostructured materials, stimulating scientists to peep into this tiny tube with ever increasing curiosity. The immediate challenge is to produce desired structural and characteristic featured carbon nanotubes in large quantities. Chemical vapor deposition is the most popular method of producing carbon nanotubes and it is of low-cost and highly useful technique for mass production of carbon nanotubes. These efforts requires not only chosen technique but also based on the precursor and the catalytic support. Glycine max oil a botanical hydrocarbon, has been found to be effective precursor for the synthesis of multi-walled carbon nanotubes (MWNTs) by Spray Pyrolysis over well dispersed Fe /Mo catalyst supported on silica at 650 °C under Ar atmosphere. As-grown MWNTs were characterized by SEM, HRTEM, Raman spectroscopy and Nitrogen adsorption studies. Raman spectroscopy revels that MWNTs are well graphitized. Dynamic and equilibrium studies of adsorption of Basic brown-4 on MWNTs were also reported.

Full Text

Reference


Alan kin-Tak Lau, David Hui, the revolutionary creation of new advanced materials carbon nanotube composites, Compos. Part B Eng, 33 (4), 263-277, (2002).

Chien, S.H., Clayton, W.R., Application of Elovich equation to the kinetics of phosphate release and sorption in soils, Soil.Sci.Soc.Am.J., 44 (2), 265-268, (1980).

Choi, Y.C., Shalin, Y.M., Lim, S.C., Bae, D.J., Lee, Y.H., Lee, B.S., Chung, D.C., Effect of surface morphology of Ni thin film on the growth of aligned Carbon nanotubes by microwave plasma-enhanced chemical vapor deposition, J.Appl. Phys. 88 (8), 4898-4903, (2000).

Du, W., Wilson, L., Ripmeester, J., Dutrisac, R., Simard, B., Denommee, S., Investigation of the pore structure of as prepared and purified Hipco single- walled carbon nanotubes by N2 ¬/Ar adsorption –implication for hydrogen storage, Nanoletters, 2, 343-346, (2002).

Ebbesen, T.W., Ajayan, P.M., Large-scale synthesis of carbon nanotubes, Nature, 358, 220-222, (1992).

Hiura, H., Ebbesen, T.W., Tanigaki, K., and Takahasi, H., Raman Studies of Carbon Nanotubes, Chem.Phys.Lett., 221, 53-58, (1993).

Ho, YS., McKay, G., Wase, Daj and Foster, C.F., study of the sorption of Divalent metal ions on to peat, Adsorp. Sci. Techno., 18, 639-650, (2000).

Iijima, S., Helical microtubules of graphitic carbon, Nature, 354, 56-58, (1991).

Jose—Yacaman, M., Miki-Yoshida, M., Rendon, L., & Santiesteban, J.G., Catalytic growth of carbon microtubules with fullerene structure, Appl.Phys. Lett. 62 (2), 202, (1993).

Kamalakaran, et al., Synthesis of thick and crystalline nanotube arrays by spray Pyrolysis, Appl.Phys.Lett., 77 (21), 3385-3387, (2000).

Karthikeyan, S., Mahalingam, P., Studies of Yield and Nature of Multiwalled Carbon nanotubes synthesized by spray pyrolysis of pine oil at different Temperatures, Int. J.Nanotech., 4(3), 189-197, (2010).

Karthikeyan, S., Mahalingam, P., Karthik, M., Large scale synthesis of carbon Nanotubes, E-Journal of Chemistry, 6 (1), 1-12, (2009).

Lagergren, S., Zur theorie der sogenannten adsorption geloster stoffe, Kungliga Svenska vetenskapskademiens, Handlingar, 24 (4), 1-39, (1898).

Mukul kumar, Yoshinori Ando, A simple method of producing aligned carbon Nanotubes from an unconventional precursor- camphor, Chem.Phys.Lett., 374 (5-6), 521-526, (2003).

Mukul Kumar, Yoshinori Ando, Single-wall and multi-wall carbon nanotubes From camphor-a botanical hydrocarbon, Diamond Relat. Mater., 12 (10-11), 1845-1850, (2003).

Rakesh A. Afre, Soga, T., Jimbo, T., Mukul Kumar, Ando et al., Carbon nano tubes by spray pyrolysis of turpentine oil at different temperatures and their Studies, Microporous Mesoporous Mater., 96 (1-3), 184-190, (2006).

Rakesh A.Afre, Soga, T., Jimbo, T., Mukul Kumar, Ando, Y., Sharon, M., Growth of vertically aligned carbon nanotubes on silicon and quartz substrate by spray pyrolysis of a natural precursor: Turpentine Oil, Chem. Phys. Lett., 414 (1-3), 6-10, (2005).

Robert J.Andrews, Catriona F. Smith, Andrew, J., Alexander, Mechanism of Carbon nanotube growth from camphor and camphor analogs by chemical Vapour deposition, Carbon, 44 (2), 341-347, (2006).

Tuinstra, F. and Koenig, J.L., Raman spectrum of Graphite, J.Chem.Phys., 53, 1126-1131 (1970).

Contact Us

Powered by

Powered by OJS