Open Access

Photocatalytic Degradation of Azo Dyes by Pure and Aluminium-doped Cadmium Oxide Nanocrystalline Thin Films

V. Radhika, radhikaviswanath@gmail.com
P.K.R Arts College for Women, Gobichettipalayam, TN, India.
V. Annamalai P.S.G College of Arts and Science, Coimbatore, TN, India.


J. Environ. Nanotechnol., Volume 9, No 4 (2020) pp. 25-33

https://doi.org/10.13074/jent.2020.12.204423

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Abstract

Pure and Al-doped Cadmium oxide (CdO) nanocrystalline thin films were synthesized by using the chemical bath deposition method and annealed at 500ËšC. The films were characterized to study their structural, optical and compositional properties. The films were used to degrade the azo dyes, methylene blue (MB) and methyl orange (MO) using photocatalytic activity (PCA). It was found that the films were capable of degrading MB up to 19% and were able to decolorize MO them up to 30%

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Ameen, S., Akhtar, M. S., Nazim, M. and Shin, H.S., Rapid photocatalytic degradation of crystal violet dye over ZnO flower nanomaterials, Mater. Lett., 96, 228-232(2013).

https://doi.org/10.1016/j.matlet.2013.01.034

Anouar Hajjaji, Atef Atyaoui, Khaled Trabelsi, Mosbah Amlouk, Latifa Bousselmi, Brahim Bessais, My Ali El Khakani and Mounir Gaidi, Cr – doped TiO2 thin films prepared by means of a magnetron sputtering process: Photocatalytic Application, Am. J. Anal. Chem., 5(8), 473-482(2014).

https://doi.org/10.4236/ajac.2014.58056

Ashok V. Borhade , Dipak R. Tope and Bhagwat K.Uphade, An efficient photocatalytic degradation of methyl blue dye by using synthesized PbO nanoparticles, E-Journal of Chemistry, 9(2), 705-715(2012).

Azadeh Tadjarodi, Mina Imani, Hamed Kerdari, Keyvan Bijanzad, Dorsan Khaledi and Maryam Rad, Preparation of CdO Rhombus – like nanostructure and its photocatalytic degradation of Azo dyes from aqueous solution, Nanomaterials and Nanotechnology, 2014.

https://doi.org/10.5772/58464

Beydoun D., R. Amal, G. Low & S. McEvoy, World Congress on Particle Technology 3, 6–9 July 1998, Brighton, UK, Paper no. 385.

Cheng, M., Zhu, m., Du, Y. and Yang, Y., Enhanced photocatalytic hydrogen evolution bsed on efficient electron transfer in triphenylamine based dye functionalized Au@Pt bimetallic core/shell nanocomposite, Int. J. Hydrog. Energy, 38(21),8631– 8638(2013).

https://doi.org/10.1016/j.ijhydene.2013.05.040

Comparelli, R., Fanizza, E., Curri, M. L., Cozzoli, P. D., Mascolo, G. and Agostiano, A., UV – induced photocatalytic degradation of azo dyes by organic – capped ZnO nanocrystals immobilized onto substrates, Appl. Catal. B Environ., 60(1-2), 01–11(2005).

https://doi.org/10.1016/j.apcatb.2005.02.013

Hamadanian, M., Behpour, M., Razavian, A. S. and Habbari, V., Structural, morphological and photocatalytic characterizations of Ag – coated anatase TiO2 fabricated by the sol – gel dip –coating method, Journal of Experimental Nanoscience, 8(7-8), pp. 901–912(2013).

https://doi.org/10.1080/17458080.2011.620018

Harraz, F. A., Mohamed, R. M., Rashad, M. M., Wang, Y. C. and Sigmund, W., Magnetic nanocomposite based on titania – silica / cobalt ferrite for photocatalytic degradation of methylene blue dye, Ceramics International, 40(1), 375–384(2014).

https://doi.org/10.1016/j.ceramint.2013.06.012

Hussein, F. H., Chemical properties of treated textile dyeing wastewater, Asian Journal of Chemistry, 25(16), 9393–9400(2013).

https://doi.org/10.14233/ajchem.2013.15909A

Jiang, T., Zhang, L., Ji, M., Wang, Q., Zhao, Q., Fu, X and Yin, H., ,Carbon nanotubes/TiO2 nanotubes composite photocatalysts for efficient degradation of methyl orange dye, Particuology, 11(6), 737– 742(2013).

https://doi.org/10.1016/j.partic.2012.07.008

Jie, R. –H., Guo, G. –B., Zhao, W. –G. and An, S. –L. Preparation and photocatalytic degradation for methyl orange of nano powder TiO2 by hydrothermal method supported on activated Carbon, Journal of Synthetic Crystals, 42(10), 2144–2149(2013).

Lee, H. U., Lee, G., Park, J. C., Lee, Y, -C., Lee, S. M., Son, B., Park, S. Y., Kim, C., Lee, S. G., Lee, S. C., Nam, B., Lee, J. W., Bae, R. D., Yoon, J. –S. and Lee, J., Efficient visible – light responsive TiO2 nanoparticles incorporated magnetic carbon photocatalysts, Chemical Engineering Journal, 240, 91–98(2014).

https://doi.org/10.1016/j.cej.2013.11.054

Nurhidayatullaili Muhd Julkapli, Samira Bagheri, and Sharifah Bee Abd Hamid, Recent advances in Heterogeneous photocatalytic decolorization of synthetic dyes, The Scientific World Journal, 692307(2014).

https://doi.org/10.1155/2014/692307

Nguyen-Phan, T. –D., Pham, V. H., Cuong, T. V., Hahn, S. H., Kim, E. J., Chung, J. S., Hur, S. H. and Shin, E. W., Fabrication of TiO2 nanostructured films by spray deposition with high photocatalytic activity of methylene blue, Mater. Lett., 64(12), 1387–1390(2010).

https://doi.org/10.1016/j.matlet.2010.03.033

Priyanka and Srivastava, V. C., Photocatalytic oxidation of dye bearing wastewater doped zinc oxide, Ind. Eng. Chem. Res., 52(50), 17790–17799(2013).

https://doi.org/10.1021/ie401973r

Rahman, M. M., Khan, B. S., Marwani, H. M., Asiri, A. M., Alamry, K. A., Rub, M. A., Khan, A., Khan, A. A. P. and Azum, N., Facile synthesis of doped ZnO – CdO nanoblocks as solid – phase adsorbent and efficient solar photocatalyst applications, J. Ind. Eng. Chem., 20(4), 2278–2286(2014).

https://doi.org/10.1016/j.jiec.2013.09.059

Rajachandrasekar, T., Selvakumar, P., Balakrishnan, K., Photocatalytic Degradation of Dichlorvos using Graphite Oxide Based Catalysts, J. Environ. Nanotechnol., 5(2), 4-10(2016).

https://doi.org/10.13074/jent.2016.06.162188

Saleh, T. A. and Gupta, V. K., Photo-catalyzed degradation of hazardous dye methyl orange by use of a composite catalyst consisting of multi-walled carbon nanotubes a titanium dioxide, J. Colloid Interface Sci., 371(1), 101-106(2012).

https://doi.org/10.1016/j.jcis.2011.12.038

Santos Fernández, R., Torres-Delgado, G., CastanedoPérez, R., Márquez-Marín, J. and Zelaya-Ángel, O,, International Materials Research Congress, 2017.

Sarkar, S. and Chattopadhyay, K. K., Visible light photocatalysis and electron emission from porous hollow spherical BiVO4 nanostructures synthesized by a novel route, Physica E: Low – dimentional systems and nanostructures, 58, 52–58(2014).

https://doi.org/10.1016/j.physe.2013.11.014

Shahmoradi, B., Maleki, A. and Byrappa, K., Removal of disperse orange 25 using in situ surface-modified iron – doped TiO2 nanoparticles, Desalination and Water Treatment, 53, 3615-3622(2013).

https://doi.org/10.1080/19443994.2013.873994

Shiragami, T., Fukami, S. Wada, Y., Semiconductor photocatalysis: effect of light intensity on nanoscale cadmium sulfide – catalyzed photolysis of organic substrates, J. Phys. Chem., 97(49), 12882–12887(1993).

https://doi.org/10.1021/j100151a041

Smith, B. A., Waters, D. M., Faulhaber, A. E., Kreger, M. A., Roberti, T. W. and Zhang, J. Z., Preparation and ultrafast optical characterization of metal and semiconductor colloidal nanoparticles, Journal of Sol–Gel Science and Technology, 9(36), 125– 137(1997).

https://doi.org/10.1023/A:1026436328858

Soltani, T. and Entezari, M. H., Photolysis and photocatalysis of methyleneblue by ferrite bismuth nanoparticles under sunlight irradiation, Journal of Molecular Catalysis A, Chemical, 377, 197– 203(2013).

https://doi.org/10.1016/j.molcata.2013.05.004

Sun, L., Shi, Y., Li, B., Li, X. and Wang, Y., Preparation and characterization of polypyrrole/TiO2 nanocomposites reverse microemulsion

polymerization and its photocatalytic activity for degradation of methyl orange under natural light, Polymer Composites, 34(7), 1076–1080(2013).

https://doi.org/10.1002/pc.22515

Ullah, K., Meng, Z. –D., Ye, S., Zhu, L. and Oh, W. –C., Synthesis and characterization of novel PbS – graphene / TiO2 composite with enhanced photocatalytic activity, J. Ind. Eng. Chem., 20(3), 1035–1042(2014).

https://doi.org/10.1016/j.jiec.2013.06.040

Zhang, J., Liu, W., Wang, X., Wang, X., Hu, B. and Liu, B., Enhanced decoloration activity by CuO@TiO2 nanobelts heterostructures via a strong adsorption – weak photodegradation process, Appl. Surf. Sci., 282, 84–91(2013).

https://doi.org/10.1016/j.apsusc.2013.05.054

Ziabari, A. A. and Ghodsi, F. E., Optoelectronic studies of sol-gel derived nanostructured CdO-ZnO composite films, J. Alloy Compd., 509(35), 8748-8755(2011).

https://doi.org/10.1016/j.jallcom.2011.06.050

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