Open Access

Growth, Structure, Spectral Characterization, Fluorescence and Thermal Studies on Phenyltrimethylammonium Trichloro Cadmiate (II) Crystals

V. Mohanraj, chemistrymohan@gmail.com
Department of Chemistry, Manonmaniam Sundaranar University Constituents College, Kanniyakumari, TN, India.
M.Thenmozhi, Department of Physics, Bangalore City College, Bangalore, Karnataka, India. R. Pavithra, Department of Chemistry, Government Arts College (Autonomous), Coimbatore, TN, India. Jaslin J. Christopher, Department of Chemistry, Manonmaniam Sundaranar University Constituents College, Kanniyakumari, TN, India. A. S. Jebamalar, Department of Physics, Nesamony Memorial Christian College, Marthandam, TN, India. R. Umarani Department of Chemistry, Government Arts College (Autonomous), Coimbatore, TN, India.


J. Environ. Nanotechnol., Volume 9, No 1 (2020) pp. 42-49

https://doi.org/10.13074/jent.2020.03.201399

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Abstract

Crystallography is a fascinating division of the entire study of the optical technology. The single crystal of Phenyl trimethyl ammonium trichloro cadmiate (II) crystals [PTMAC (II)] was grown by slow evaporation technique at room temperature. The grown crystals were characterized using CHN analysis, FT-IR, 1H NMR spectra to confirm with functional groups and structures in spectroscopy methods. TG/TDA analysis were used to find out the thermal stability of grown crystals and fluorescence studies were also carried out, followed by single crystal X-ray diffraction studies by using SHELXL and refined by full matric latest square methods. The molecule belongs to monoclinic crystal system with C2i/n space group. Focus has been laid on the phase transition of crystals which makes the study interesting; moreover, inorganic crystals are being used for many applications in the field of computer technology.

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Reference


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