Open Access

Hard Water Tolerance of Mixed Surfactant Systems Containing Sodium Dodecyl Sulfate and Decyl Polyglucoside

Geetha Dass, geethachem2015@gmail.com
Department of Chemistry, Kalasalingam Academy of Research and Education, TN, India.
M. S. Revathy, Department of Physics, Kalasalingam Academy of Research and Education, TN, India. P. Manorama, Department of Chemistry, Kalasalingam Academy of Research and Education, TN, India. Ashok Kumar, Department of Chemistry, Kalasalingam Academy of Research and Education, TN, India. Ramesh Department of Chemistry, Kalasalingam Academy of Research and Education, TN, India.


J. Environ. Nanotechnol., Volume 8, No 4 (2019) pp. 23-25

https://doi.org/10.13074/jent.2019.12.194380

PDF


Abstract

The objective of this research was to evaluate the efficiency of the mixed micelles of glucoside-sodium dodecyl sulfate surfactant for estimation of water hardness. The non-ionic glucoside surfactants have proved themselves as potential alternatives to the cleaning and washing commodity market, exhibiting effective hard water tolerance. The suitability of the glucoside surfactant for the lime soap dispersion ability was determined through the mixed micellization studies. The effect of incorporation of synthesized decyl polyglucoside to the anionic sodium dodecyl sulphate surfactant on the water hardness tolerance has been investigated through nephelometric measurements. No turbidity was observed up to 350 ppm hardness of water beyond 10% level of incorporation of APG10. The plots of turbidity against water hardness for 1:0, 4:1, 2:1 and 1:1 calcium to magnesium ratio have revealed a linear variation of turbidity with hardness for a fixed surfactant concentration at 2.5 mM.  In comparison, decyl polyglucoside was found to be better in hard water tolerance than anionic surfactants. Hence, it was concluded that with moderate foaming, decyl glucoside would be a better surfactant for making detergents to face water crisis.

Full Text

Reference


Ansari, W. H., Aslam, J., Siddiqui, U. S. and Kabir-ud-Din, Micellar growth of m-2-m type gemini surfactants (m = 10, 12, 14) with higher chain length alcohols/amines (C6–C8) in the absence and presence of organic salts (sodium salicylate, sodium tosylate), J. Mol. Liq., 174, 05-10 (2012)

https://dx.doi.org/10.1016/j.molliq.2012.07.014

El-Sukkary, M. M. A., Nagla A. Syed., Ismail Aiad and El-Azab, W. I. M., Synthesis and characterization of some alkyl polyglycosides surfactants, J. Surfact. Deterg., 11(2), 129-139(2008).

https://dx.doi.org/10.1007/s11743-008-1063-9

Geetha, D. and Tyagi, R., Alkyl Poly Glucosides (APGs) surfactants and their properties: A Review, Tenside Surf. Det., 49(5), 417-427 (2012).

https://dx.doi.org/10.3139/113.110212

Geetha, D. and Tyagi, R., Synergistic interactions in the mixed micelles of cationic amphiphile with biopolymeric glucoside surfactants, J. Dispers. Sci. Technol., 37(8), 1089-1096 (2016)

https://dx.doi.org/10.1080/01932691.2015.1081097

Geetha, D. and Tyagi, R., Surface and dispersion properties of dodecanol and tetradecanol based glucoside surfactants, Int. J. Sci. Eng. Res., 5(4), 1278- 1283(2014).

Naorem Homendra and Ch. Indira Devi, Turbidity studies on mixed surfactant systems in hard water: A new method for estimation of water hardness, Indian J. Chem. Technol., 11, 7 83-786(2004).

Naved Azum, Khalid A., Alamry, Sher Bahadar Khan, Malik Abdul Rub, Abdullah M., Asiri1 and Yasir Anwar, Synergistic interaction between anionic and nonionic surfactant: Application of the mixed micelles templates for the synthesis of silver nanoparticles, Int. J. Electrochem. Sci., 11, 1852 – 1867 (2016).

Poonam Sharma, Shweta Sachar, Gurpreet Kaur, Pankaj Thakur, Mandeep Singh Bakshi and Tarlok Singh Banipal, Mixed micelle behavior of dodecyl-β-D-glucopyranoside with cationic gemini surfactants: A fluorescence study, J. Surface Sci. Technol., 23(3), 131-147 (2007).

https://dx.doi.org/10.18311/jsst/2007/1928

Contact Us

Powered by

Powered by OJS