Open Access

Developmental Studies on Novel Biodegradable Polyester Films from Maravetti Oil

T. Sahaya Maria Jeyaseeli , Department of Chemistry, Sarah Tucker College (Autonomous), Tirunelveli, TN, India. I. Antony Danish , Department of Chemistry, Sadakathullah Appa College (Autonomous), Tirunelveli, TN, India. J. Shakina shakinajudson@gmail.com
Department of Chemistry, Sarah Tucker College (Autonomous), Tirunelveli, TN, India.


J. Environ. Nanotechnol., Volume 8, No 4 (2019) pp. 01-07

https://doi.org/10.13074/jent.2019.12.194379

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Abstract

          A unique biodegradable polyester film was made from naturally accessible Maravetti crude (Hydnocarpus wightianus), formic acid and 30% hydrogen peroxide, using a step-wise polymerization technique. The polymer was created by reacting resin with styrene. UV, FTIR and NMR spectral studies were carried out to identify the structural characteristics of the polymer product. The biodegradability of the polyester film was investigated using Soil burial test. The thermal deterioration was investigated using TG-DTA analysis at various time intervals. The cross-linking potential of the polymers was determined using DSC analysis. Tensile and impact strengths and other mechanical parameters were assessed. The resultant polymers were found to have acceptable mechanical characteristics and cured quickly.

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Reference


David K. A. Barnes, Francois Galgani, Richard C. Thompson and Morton Barlaz, Accumulation and fragmentation of plastic debris in global environments, Philos. Trans. R. Soc. Lond. B: Biol. Sci., 364(1526), 1985–1998 (2009).

https://dx.doi.org/10.1098/rstb.2008.0205

Rohan Dassanayake, S., Sanjit Acharya, Noureddine Abidi, Biopolymer-based materials from polysaccharide properties, processing, characterization and sorption Applications, Advanced Sorption Process Applications (2018).

https://dx.doi.org/10.5772/intechopen.80898

Birendra Pratap Singh, Jai Prakash Singh, Shruti Shukla, Shanti Sharma, Synthesis and characterization of inorganic polymer nano-composites, Der Chemica Sinica, 3(2), 521-526 (2012).

Norton, S. A., Useful plants of dermatology, I. Hydnocarpus and chaulmoogra, J. Am. Acad. Dermatol., 31(4), 683-686 (1994).

https://dx.doi.org/10.1016/s0190-9622

Prabha Littis, G. S., Malar, S. and Begila David, Studies on polyester elastomers using palm olein for drug delivery, Int. J. Sci. Eng. Appl. Sci., 1(5), 142-148 (2015).

Priya Rajini, K. and Begila David, S., Synthesis and comparative study of novel cross linked biopolymers from Linseed Oil, Int. J. Eng. Res. Appl., 5(8), 09-15 (2015).

Roland Geyer, Jenna Jambeck, R. and Kara Lavender, Law, Production, use and fate of all plastics ever made, Sci. Adv., 3(7), 01-05 (2017).

https://dx.doi.org/10.1126/sciadv.1700782.

Sathishkumar, T. P., Navaneethakrishnan, P. and Shankar, S., Characterization of natural fiber and composites-A review, J. Reinf. Plast. Compos., 32(19), 1457-1476 (2013).

https://dx.doi.org/10.1177/0731684413495322

Shakina, J., Anita, A. and Alamelu, K., Polymers from renewable resources: polyester resin based upon acid anhydride-cured hydroxylated soybean oil, Indian J. Sci., 8(20), 44-54 (2014).

Shakina, J , Sathiya Lekshmi, K. and Allen Gnana Raj, G., Microbial degradation of synthetic polyesters from renewable resources, Indian J. Sci., 1(1), 21-28 (2012).

Shakina, J., Sathiya Lekshmi, K. and Allen Gnana Raj, G., Synthesis and characterisation of Novel cross linked biopolyesters from olive oil as eco-friendly biodegradable materials, E-J Chem., 9(1), 181-192(2012).

Li, Y. T., Yang, L. T., Zhang, H. and Tang, Z. J., Synthesis and properties of a novel bio based polymer from modified soy bean oil, IOP Conf. Series: Mater. Sci. Eng., 17, 012010 (2017).

https://dx.doi.org/10.1088/1757-899X/170/1/012010

Wang, H. J., Rong, M. Z. and Zhang, M. Q., Biodegradable foam plastics based on castor oil, Biomacromolecules, 9(2), 615-623 (2008).

https://dx.doi.org/10.1021/bm7009152

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