Thermodynmic Properties and Interaction Abilities of Ternary Liquid Mixtures at 308.15K and 318.15K
J. Environ. Nanotechnol., Volume 7, No 3 (2018) pp. 22-33
Abstract
Experimental densities, viscosities and ultrasonic velocities were measured for ternary liquid mixtures of diethylmalonate+ 1, 4-dioxane with cyclohexane and n-hexane at 308.15K and 318.15K and atmospheric pressure over the entire range of mole fractions. The calculated thermodynamic properties and some excess parameters such as VE, ΔKs, Δɳ, ΔVF, ΔLF, ΔβΤ, were calculated and applied to Redlich − Kister polynomial equation to determine the appropriate coefficients. The deviations of the ternary mixtures from its ideal behaviour were determined and the interaction ability of the liquids in the ternary liquid mixtures was studied.
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Reference
Ali, A., Nain, A. K., Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C, Pramana., 58, 695 (2002).
https://doi.org/10.1007/s12043-002-0026-3
Acree, W. E., Thermodynamic Properties of Non-Electrolyte Solutions, Academic Press, NewYork, 1948.
Awasthi, A., Rastogi, M., Gupta, M., Shukla, J. P., Ultrasonic investigation of molecular association in ternary mixtures, J. Mol. Liq. 80(1), 77–88 (1999).
https://doi.org/10.1016/S0167-7322(99)00016-1
Baluja, S., Pandya, N., Kachhadia, N., Solanki, A., Inamdar, P., Thermodynamic and acoustical studies of binary mixtures of diethyl malonate at 308.15K, Phys. Chem. Liq., 43(3), 309–316(2005).
https://doi.org/10.1080/00319100500096940
Canosa, J., Rodrı́guez, A., Tojo, J., Binary mixture properties of diethyl ether with alcohols and alkanes from 288.15 K to 298.15 K, Fluid Phase Equilib., 156(1–2), 57–71(1999).
https://doi.org/10.1016/S0378-3812(99)00032-1
Gad Shayne, C., Encyclopaedia of Toxicology, 978, 4822
Giner, B., Martín, S., Artigas, H., López, M. C., Lafuente, C., Study of Weak Molecular Interactions through Thermodynamic Mixing Properties, J. Phys. Chem. B., 110(35), 17683–17690 (2006).
https://doi.org/10.1021/jp062583q
Gokavi, G. S., Raju, J. R., Aminabhavi, T. M., Balundgi, R. H., Muddapur, M. V., Viscosities and densities of binary liquid mixtures of dimethyl sulfoxide with chlorobenzene, pyridine, and methyl ethyl ketone at 25, 35, 45 and 55.degree.C, J. Chem. Eng. Data., 31(1), 15–18 (1986).
https://doi.org/10.1021/je00043a004
Jacobson, B., Ultrasonic Velocity in Liquids and Liquid Mixtures, J. Chem. Phys., 20(5), 927–928 (1952).
https://doi.org/10.1063/1.1700615
Jacobson, B., Gralén, N., Ehrensvärd, G., Intermolecular Free Lengths in Liquids in Relation to Compressibility, Surface Tension and Viscosity., Acta Chem. Scand., 5, 1214–1216 (1951).
https://doi.org/10.3891/acta.chem.scand.05-1214
Nain, A. K., Chandra, P., Pandey, J. D., Gopal, S., Densities, Refractive Indices, and Excess Properties of Binary Mixtures of 1,4-Dioxane with Benzene, Toluene, o -Xylene, m -Xylene, p -Xylene, and Mesitylene at Temperatures from (288.15 to 318.15) K, J. Chem. Eng. Data., 53(11), 2654–2665 (2008).
https://doi.org/10.1021/je800579j
Nayak, J. N., Aralaguppi, M. I., Aminabhavi, T. M., Density, Viscosity, Refractive Index, and Speed of Sound in the Binary Mixtures of 1,4-Dioxane + Ethyl Acetoacetate, + Diethyl Oxalate, + Diethyl Phthalate, or + Dioctyl Phthalate at 298.15, 303.15, and 308.15 K, J. Chem. Eng. Data., 48(6), 1489–1494 (2003).
https://doi.org/10.1021/je0301489
Price, D. M., Temperature calibration of differential scanning calorimeters, J. Therm. Anal., 45(6), 1285–1296 (1995).
https://doi.org/10.1007/BF02547423
Rathnam, M., Mohite, S., Kumar, M., Volumetric, viscometric and optical study of molecular interactions in binary mixtures of diethyl malonate with ketones at 303.15, 308.15 and 313.15K, J. Serbian Chem. Soc., 77(4), 507–521 (2012).
https://doi.org/10.2298/JSC110712198R
Redlich, O., Kister, A. T., Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 40(2), 345–348 (1948).
https://doi.org/10.1021/ie50458a036
Rowlinson, J.S., Swinton, F., Liquids and liquid mixtures, 3rd ed., Butterworth-Heinemann, London, 2013.
Suryanarayana, C. V. and Kuppusamy, J., Free volume and internal pressure of liquid from ultrasonic velocity, J. Acoust. Soc. India., 4, 75 (1976).
Umasivakami, K., Vaideeswaran, S., Rose, V., Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K, J. Serbian Chem. Soc., 83(10), 1131–1142 (2018).
