Open Access

Dynamic and Equilibrium Studies on Adsorption of Direct Dye (Direct Yellow 28) by Low Cost Activated Carbon Derived from Jatropha curcas Stem Waste

K. Sakthivel , Department of Chemistry, Periyar University, Salem, TN, India. B. Sivakumar , Department of Chemistry, Angel College of Engineering and Technology, Tirupur, TN, India. K. Gopal, Department of Chemistry, Erode Arts & Science College, Erode, TN, India. C. Kannan chellapandiankannan@gmail.com
Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli, TN ,India.


J. Environ. Nanotechnol., Volume 4, No 3 (2015) pp. 74-81

https://doi.org/10.13074/jent.2015.09.153161

PDF


Abstract

Activated carbon materials were prepared from abundantly available Jatropha Curcas stem waste. The carbon samples were prepared by subjecting the carbon material to various chemical processes. The adsorption capacity of selected derived carbon sample using Jatropha Curcas stem waste prepared by Dolomite process(CaCO3) was much greater than the capacities of the other carbons prepared by various processes. The adsorption of Direct Dye (Direct Yellow 28) on this dolomite treated activated carbon was investigated to assess the possible use of this adsorbent for the processing of Textile dyeing Effluent wastewater. The effect of major Variables governing the efficiency of process such as initial dye concentration, agitation time and temperature on the adsorption capacity has been studied. The percentage removal of dye is observed to decrease with the increase in initial dye concentration. With increase in temperature, the adsorption of dye also decreases, indicating exothermic nature of the reaction. Adsorption isothermal data could be interpreted by the Langmuir and Freundlich equations. Kinetic data have been studied using Elovich, Pseudo-first order and Pseudo-second order equations for understanding the reaction mechanism. The result have established good potentiality for the Activated Carbons material to be used for the adsorption of Direct Yellow 28 from wastewater

Full Text

Reference



Allen, S. J. and Koumanova, B.. Decolourisation of waste/water using adsorption (review), Journal of the University of Chemical Technology and Metallurgy, 40(3), 175-192(2005).

Ann, H. K., Park, B.Y. and Kim, D.S., Crab shell for the removal of heavy metals from aqueous solution, Wat. Res.,35, 3551-3556(2001).

Banerjee, S. K., Majmudar, S., Roy, A. C., Banerjee, S. C. and Banerjee, D. K., Activated carbon from coconut shell, Indian J. Technol., 14,45(1976).

Benefield, L. D., Judkins, J. F. and Weand, B. L., Process chemistry for water and wastewater treatment, Prentice-Hall, Englewood Cliffs, NJ(1982).

Bousher, A., Shen, X. and Edyvean, R. G., Removal of colored organic matter by adsorption on to low cost waste materials, J. Water Res., 31,2084(1997).

Brown, P., Jefcoat, I. A., Parrish, D., Gill, S. and Graham, E., Evaluation of the adsorptive capacity of peanut hull pellets for heavy metals in solution, Adv. Environ. Res.,4, 19-29(2000).

Chien, S. H. and Clayton, W., Application of elovich equation to the kinetics of phosphate release and sorption in soils, J. Am. Soil Sci. Soc., 44, 265–268(1980).

Crini, G, Non-Conventional low-Cost adsorbents for dye removal: A review, Bioresource Technol., 97, 1061-1085(2006).

Freundlich, H., Colloid and Chemistry, London Methien (1926).


Ho, Y. S. and McKay, G., Study of the sorption of divalent metal ions onto peat, Adsorpt. Sci. Technol., 18, 639-650(2000).

Jambulingam, M., Renugadevi, N., Karthikeyan, S., Kiruthika, J. and Pattabi, S., Adsorption of Cr(VI) from aqueous solution using a low cost activated carbon, Indian J. Environ. Protect., 25(5), 458-463(2005).

Jambulingam, M., Renugadevi, N., Karthikeyan, S., Kiruthika, J. and Pattabi, S., Adsorption of Cr(VI) from aqueous solution using a low cost activated carbon, Indian J. Environ. Protect., 25(5), 458-463(2005).

Karthikeyan S., Jambulingam M., Sivakumar P. and Saminathan, S., International Conference on Resource Utilization and Intelligent Systems. [INCRUIS 2001], Erode, 4(2001).

Karthikeyan S., Jambulingam M., Sivakumar P., Shekhar A. P. and Krithika, J., Impact of textile effluents on fresh water fish Mastacembelus armatus (Cuv. & Val), J. Chem., 3(4), 303(2006).

Karthikeyan, S. and Sivakumar, P., The Effect of activating agents on the activated carbon prepared from Feronia limonia (L.) Swingle (Wood Apple) Shell, J. Environ. Nanotechnol., 1(1), 5-12(2012).

Karthikeyan, S., Bhuvaneswari, G., Malathi, S., Maheswari, P. and Sivakumar, B., Studies on removal of  textile effluents using Ipomea carnea stem waste activated carbon, J. Ind. Council Chem., 24(2), 63-67(2007).

Karthikeyan, S., Sivakumar, P. and Palanisamy, P. N., Novel activated carbons from agricultural wastes and their characterization, E-J. Chem., 5, 409-426(2008).

Kweon, D. K., Choi, J. K., Kim, E. K. and Lim, S. T., Adsorption of divalent metal ions by succinylated and oxidized corn starches, Carbohydr. Polym., 46, 171-177(2001).

Low, K. S., Lee C. K. and Ng,  A. Y., Column study on the adsorption of Cr(VI) using quanternised rice hulls, Bioresour. Technol., 65, 205(1999).

Low, K. S. and Lee, C. K., Quaternized rice husk as sorbent for reactive dyes, Bioresour. Technol., 61, 121-125(1997).

Macías-García, A., Valenzuela, C., Gomez Serrano, V. and Espinosa-Mansilla, A., Adsorption of Pb2+ by heat-treated and sulfurized AC, Carbon., 31,1249-1255(1993).

Marshall, W. E. and Johns, M. M., Agriculctural by products as metal adsorbents: sorption properties and resistance to mechanical abrasion, J. Chem. Tecnol. Biotechnol., 66, 192-198(1996).

Nabi Bindhendi Gh, R., Torabian, A., Ehsani, H., Razmkhah, N. and Abbasi, M., Int. J. Environ. Res., 1(3), 242(2007).

Nagarnaik, P. B., Bhole, A. G. and Natarajan, G. S., Adsorption of arsenic on fly ash, Ind. J. Env. Hlth., 45, 1(2003).

Namasivayam, C. and Yamuna, R. T., Studies on chromium(III) removal from aqueous solution by adsorption onto biogas residual slurry and its application to tannery wastewater treatment, Wat. Air. soil pollut., 113, 371-384(1999).

Sivakumar, B., Kannan, C. and Shanthi, P., Kinetics for removal of reactive blue 2 from aqueous solution on the nanoporous carbon materials prepared from Balsamodendron caudatum wood waste, J. Environ. Nanotechnol., 1(1), 20-27(2012).

Wang, Y. C., Szeto, Y. S., Cheung, W. H. and McKay, G., Equlibrium studies for acid dye adsorption onto chitosan Langmuir., 7888(2003).

Yoshida, H., Fukuda, S., Okamota, A. and Kataoko, T., Adsorption of acid dye on cross-linked chitosan fibers: Equilibria, Chem. Eng. Sci., 48, 2267-2272(1993).

Contact Us

Powered by

Powered by OJS