Growth, Spectral, Structural and Thermal Properties of Inorganic Materials TetrabutylammoniumTetrabromoCobaltate (II) Crystal
J. Environ. Nanotechnol., Volume 4, No 2 (2015) pp. 65-74
Abstract
Single crystals of Tetrabutylammoniumtetrabromocobaltate (II) crystal, was grown by slow evaporation method at room temperature. The crystals belong to a class of compounds that shown interesting properties like phase transitions and ferroelectric behaviour in a narrow temperature. The grown crystals were characterized through elemental analysis, powder X-ray diffraction, thermogravimetric analysis, differential thermal analysis, low temperature differential scanning calorimetry techniques. The spectral studies of FTIR, 1H and 13C NMR spectra were obtained for the sample. Single crystal X-ray diffraction technique is used to find the structure and crystal packing of the compounds.
Full Text
Reference
Amirthaganesan, G., Kandhaswamy, M. A. and Srinivasan, V., Synthesis, characterization and structural phase transition studies in trismethylammoniumpentachloro barium dihydrate single crystals, Cryst. Res. Technol., 38(10), 910-912 (2003).
doi:10.1002/crat.200310111
Byrappa, K., Kandhaswamy, M. A. and Srinivasan,V., Growth, Morphology, Structure and Properties of Na3BaCl5 2H2O Crystals, Cryst. Res. Technol., 34(7), 143-150(1999).
doi:10.1002/(SICI)1521-4079(199908)34:7 <843 ::AID-CRAT843 >3.0.CO;2-W
Eychmuller, A., Rogach, A. L., Chemistry and photophysics of thiol-stabilized II-VI semiconductor nanocrystals, Pure Appl. Chem., 72(1), 179-188(2000).
doi:10.1351/pac200072010179
Iwata, M., and Ishibashi, Y., Dielectric dispersion in [N(C2H5)4]2ZnCl4 Single Crystal, Lett, 60(10), 3245-3248(1991).
doi:10.1143/JPSJ.60.3245
Kahrizi, M. and M. O., Steinitz Solid State Communication, Sciencedirect, 74(5), 333-335, (1990).
doi:10.1016/0038-1098(90)90497-Y
Koopmans, B., Anema, A., Jonkman, H. T., Sawatzky, G. A. and Van der Woude, F., Resonant-optical-second-harmonic generation from thin C60 films, Phys. Rev., 48(4), 2759-2770 (1993).
doi:10.1103/PhysRevB.48.2759
Koopmans, B., Janner, A. M., Jonkman, H. T., Sawatzky, G. A. and Van der Woude, F., Strong bulk magnetic dipole induced second-harmonic generation from C60, Phys. Rev. Lett., 71(21), 3569-3580(1993).
doi:10.1103/PhysRevLett.71.3569
Maurya, R. C., Sharma, P., Roy, S., Synthesis and characterization of some mixedâ€ï¿½ligand picrate complexes of Nickel(II) involving heterocyclic nitrogen donors, Synth. React. Inorg. Metal. Org. Chem., 33(4), 683-698 (2003).
doi:10.1081/SIM-120020332
Moore, C. M. S., Hackman, Brennan, T. and Minteer, S. D., Effect of mixture casting phosphonium salts with Nafion® on the proton exchange capacity and mass transport through the membranes, J. Membr. Sci., 254(1), 63-70 (2005).
doi:10.1016/j.memsci.2004.11.027
Petrosyan, H. A., Karapetyan, H. A., Yu Antipin, M., Petrosyan, A. M., Nonlinear optical crystals of l-histidine salts, J. Cryst. Growth, 275(1), 1919-1925(2005).
doi:10.1016/j.jcrysgro.2004.11.258
Sawada, S., Takashige, M., Shimizu, F., Suzuki, H., and Yamaguchi, T., Ferroelectricity in A 2 BX 4-type halide compounds, Ferroelectrics, 169(1), 207-214 (1995).
doi:10.1080/00150199508217331
Shuai, Z., Bredas, Magnetic dipole and electric quadrupole contributions to second-harmonic generation in C60-A valence effective hamiltonian study, J. L., Adv. Mater, 6(6), 486-488 (1994).
doi:10.1002/adma.19940060610
Xue, D., Ratajczak, H., Effect of hydrogen bonds on physical properties of ammonium dihydrogenphosphate crystals, J. Mol. Struct., 716(1), 207-210(2005).
doi:10.1016/j.theochem.2004.11.026
Young Kim, D., Kwun, S., Gul Yoon, Linear birefringence behavior of A2BX4-type ferroic crystals in the normal-incommensurate phase transition, J., Phys. Rev., 57(18), 11173-11185 (1998b).
doi:10.1103/PhysRevB.57.11173