Open Access

Utilization of Nanosilica in M50-grade Concrete: Mechanical and Microstructural Performance for Sustainable Construction

Sheena A D, dr.sheenaad@gmail.com
Department of Civil Engineering, Vels Institute of Science, Technology and Advanced Studies (VISTAS), Chennai, TN, India
ORCID
Beena Mol M, beenamol@lbscek.ac.in
Department of Civil Engineering, LBS Institute of Technology for Women, KL, India
ORCID
Sashmitha S, sashmithashankar10@gmail.com
Department of Civil Engineering, C. K. College of Engineering and Technology, Cuddalore, TN, India
ORCID
Pachaivannan Partheeban parthi011@yahoo.co.in
Department of Civil Engineering, Chennai Institute of Technology (CIT), Chennai, TN, India



J. Environ. Nanotechnol., Volume 15, No 2 (June 2026) pp. 43-51

https://doi.org/10.13074/jent.2026.06.2612005

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Abstract

The growing demand for green building materials has spurred the development of strategies to partially replace cement with nanoengineered additives, thereby minimizing the ecological footprint. This study evaluates the properties of M50-grade high-strength concrete with nanosilica (NS) as a partial replacement for cement, which can also assist in the reduction of CO2 emissions into the atmosphere. Due to its high reactivity and small particle size, nanosilica was used as a partial replacement for cement at 0%, 5%, 10%, and 15% by weight. Mechanical properties, including compressive strength, split tensile strength, and flexural strength, were evaluated at various curing ages to identify the optimal replacement level. For microstructural characterization, separate experiments were carried out using Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD) techniques to examine the formation of calcium silicate hydrate (C–S–H) gel and the refinement of the pore structure. The test results show that the addition of nanosilica improves the strength properties of the mix up to an optimum replacement level of 15%. At 28 days, the mix with 15% NS exhibited superior properties compared with all other mixes. The mix with 15% NS replacement exhibited a compressive strength of 58.21 N/mm², a split tensile strength of 8.83 N/mm², and a flexural strength of 5.34 N/mm². Thus, a 15% NS replacement level is optimal for producing high-strength M50-grade concrete suitable for environmentally friendly construction. The study further demonstrates that nanosilica is effective in developing sustainable concrete mixes through its use as a supplementary cementitious material.

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Reference


Al-Hadithi, A. I. and Hilal, N. N., The Possibility of Enhancing Some Properties of Self-Compacting Concrete by Adding Waste Plastic Fibers, J. Build. Eng., 8, 20–28(2016).

https://doi.org/10.1016/j.jobe.2016.06.011

Al-hagri, M. G. and Mahmud, S. D., Effect and Optimization of Incorporation of Nano-SiO2 into Cement-Based Materials – a Review, Challenge J. Concrete Res. Lett., 13(1), 36–53 (2022).

https://doi.org/10.20528/cjcrl.2022.01.004

Al-saffar, F. Y., Sing, L. W. and Paul, S. C., An Elucidative Review of the Nanomaterial Effect on the Durability and Calcium-Silicate-Hydrate (C-S-H) Gel Development of Concrete, Gels, 9(8), 613(2023).

https://doi.org/10.3390/gels9080613

ASTM C1202, Standard Test Method for Electrical Indication of Concrete’s Ability to Resist Chloride Ion Penetration, ASTM International, West Conshohocken, PA, USA, 2019.

ASTM C150: Standard Specification for Portland Cement, ASTM International, West Conshohocken, PA, USA, 2024.

Charkhtab, M. S., Rahmat, M., Morteza, J. and Iman, N. M., Mechanical Properties of Fly Ash-Based Geopolymer Concrete with Crumb Rubber and Steel Fiber under Ambient and Sulfuric Acid Conditions, Constr. Build. Mater., 281, 122571(2021).

https://doi.org/10.1016/j.conbuildmat.2021.122571

Christensen, T. H., A. Damgaard, A., Levis, J., Zhao, Y., Bjorklund, A., Arena, U., Barlaz, M. A., Starostina, V., Boldrin, A., Asrup, T. F. and Bisinella, V., Application of LCA Modelling in Integrated Waste Management, Waste Manage., 118, 313–22(2020).

https://doi.org/10.1016/j.wasman.2020.08.034

Gopinath, S., Mouli, P. C., Murthy, A. R., Iyer, N. R. and Maheswaran, S., Effect of Nanosilica on Mechanical Properties and Durability of Normal Strength Concrete, Arch. Civ. Eng., 58(4), 433–444(2012).

https://doi.org/10.2478/v.10169-012-0023-y

IS 10262, Guidelines for concrete mix design proportioning, Bur. Indian Stand. New Delhi. (2019) 1–14.

IS 12269 (1987): 53 grade ordinary Portland cement.

IS 383: Coarse and Fine Aggregate for Concrete – Specification: 2016

IS 456 (2016): Plain and Reinforced Concrete - Code of. Practice 2016

IS 516 - 2018, Method of Tests for Strength of Concrete, Bur. Indian Stand. (2018) 1–30.

IS 5816-2018, Indian standard Splitting tensile strength of concrete- method of test, Bur. Indian Stand. (2018) 1–14.

Jo, B. W., Kim, C. H., Tae, G. H. and Park, J. B., Characteristics of Cement Mortar with Nano-SiO2 Particles, Constr. Build. Mater., 21(6), 1351–1355(2007).

https://doi.org/10.1016/j.conbuildmat.2005.12.020

Khan, K., Ahmed, W., Amin, M. N. and Nazar, S., Nanosilica-Modified Concrete: A Bibliographic Analysis and Comprehensive Review of Material Properties, Nanomater., 12(12), 1989(2022).

https://doi.org/10.3390/nano12121989

Mukharjee, B. B. and Barai, S. V., Influence of Nanosilica on the Properties of Recycled Aggregate Concrete, Constr. Build. Mater., 55, 29–37(2014).

https://doi.org/10.1016/j.conbuildmat.2014.01.003

Mustakim, S. M., Das, S. K., Mishra, J., Asif, A., Thamar, A. S., Hasan, A. S. and Kaze, C. R., Improvement in Fresh, Mechanical and Microstructural Properties of Fly Ash- Blast Furnace Slag Based Geopolymer Concrete By Addition of Nano and Micro Silica, Silicon, 13(8), 2415–2428(2021).

https://doi.org/10.1007/s12633-020-00593-0

Nazari, A. and Shadi, R., Retraction Note to: Effects of CuO Nanoparticles on Compressive Strength of Self-Compacting Concrete, Sadhana, 47(4), 264(2022).

https://doi.org/10.1007/s12046-022-02043-6

Senff, L., João, A. L., Victor, M. F., Dachamir, H. and Wellington, L. R., Effect of Nanosilica on Rheology and Fresh Properties of Cement Pastes and Mortars, Constr. Build. Mater., 23(7), 2487–2491(2009).

https://doi.org/10.1016/j.conbuildmat.2009.02.005

Shafi, L. S., Megha, G. and Geeta, M., Comparative Study of Nanosilica Induced Mortar, Concrete and Self-Compacting Concrete – A Review, Ind. J. Sci. Technol., 9(44), (2016).

https://doi.org/10.17485/ijst/2016/v9i44/105288

Su, X., Andoh, A. R., Cai, H., Pan, J., Amr, K. and Said, H. M., GIS-Based Dynamic Construction Site Material Layout Evaluation for Building Renovation Projects, Automat. Constr., 27, 40–49(2022).

https://doi.org/10.1016/j.autcon.2012.04.007

Tanimola, J. O. and Steve, E., Recent Advances in Nano-Modified Concrete: Enhancing Durability, Strength, and Sustainability through Nanosilica (NS) and Nano Titanium (NT) Incorporation, Appli. Eng. Sci., 19, 100189(2024).

https://doi.org/10.1016/j.apples.2024.100189

Tsampali, E., Eirini, C. T., Eleni, P. and Maria, S., The Mechanism Action of Crystalline Admixtures on Hydration, Microstructure, and Self-Healing of Cementitious Materials, J. Build. Eng., 110, 112987(2025).

https://doi.org/10.1016/j.jobe.2025.112987

Yu, R., Tang, P., Spiesz, P. and Brouwers, H. J. H., A Study of Multiple Effects of Nanosilica and Hybrid Fibres on the Properties of Ultra-High Performance Fibre Reinforced Concrete (UHPFRC) Incorporating Waste Bottom Ash (WBA), Constr. Build. Mater., 60 98–110(2026).

https://doi.org/10.1016/j.conbuildmat.2014.02.059

Zhan, P., Jing, X., Juan, W., Junqing, Z. and Zhihai, H., A Review of Recycled Aggregate Concrete Modified by Nanosilica and Graphene Oxide: Materials, Performances and Mechanism, J. Clean. Prod., 375 134116(2022).

https://doi.org/10.1016/j.jclepro.2022.134116

Zhang, T., Qijun, Y., Jiangxiong, W. and Jianxin, L., Investigation on Mechanical Properties, Durability and Micro-Structural Development of Steel Slag Blended Cements, J. Therm. Anal. Calorim., 110 (2), 633–639(2012).

https://doi.org/10.1007/s10973-011-1853-6

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