Open Access

Innovative Utilization of Wet Blue Leather Waste to Nitrogen-doped Activated Carbon for High-performance Supercapacitors

S. Yuvaraj, yuvachem08@gmail.com
Department of Chemical Engineering, Kongu Engineering College, Erode, TN, India
V. Sampathkumar, Department of Civil Engineering, Kongu Engineering College, Erode, TN, India S. Manoj, Department of Civil Engineering, Kongu Engineering College, Erode, TN, India S. Esakkiraj, Department of Chemical Engineering, Kongu Engineering College, Erode, TN, India M. Sudhan Prabhakaran, Department of Chemical Engineering, Kongu Engineering College, Erode, TN, India S. Yuvaraj Department of Chemical Engineering, Kongu Engineering College, Erode, TN, India


J. Environ. Nanotechnol., Volume 14, No 1 (2025) pp. 30-36

https://doi.org/10.13074/jent.2025.03.2511238

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Abstract

With the growing need for sustainable energy storage solutions, this study explores a new way to create eco-friendly, cost-effective materials for supercapacitors. We focused on wet blue leather, a by-product of the leather tanning industry, and turned it into nitrogen-doped activated carbon for use in supercapacitors. The process involved first carbonizing the leather scraps at 800 ℃, then activating the carbon with sulfuric acid and doping it with nitrogen using ammonia from urea. To evaluate the performance of the material, we used several characterization methods, including scanning electron microscopy (SEM), particle size analysis, X-ray diffraction (XRD), and various electrochemical tests. The results showed that the activated carbon, particularly the nitrogen-doped sample, had a highly porous structure, which is key for good supercapacitor performance. Nitrogen doping enhanced its capacitance and energy storage capacity. Electrochemical tests indicated that the material performed well at low frequencies. Galvanostatic charge-discharge tests revealed a balance between energy and power density, with the nitrogen-doped carbon excelling at lower current densities, making it ideal for applications that require high energy storage and long-term stability. Overall, this study demonstrates that nitrogen-doped activated carbon from leather waste is a promising, sustainable alternative for high-performance supercapacitors, offering both environmental and economic benefits.

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Reference


Bang, J. H., Lee, H. M., An, K. H. and Kim, B.J., A study on optimal pore development of modified commercial activated carbons for electrode materials of supercapacitors, Appl. Surf. Sci., 415, 61-66(2017).

https://doi.org/10.1016/j.apsusc.2017.01.007

Bhatnagar, A., Sillanpää, M. and Witek-Krowiak, A., Agricultural waste peels as versatile biomass for water purification—A review, Chem. Eng. J., 270, 244-271(2015).

https://doi.org/10.1016/j.cej.2015.01.135

Bora, M., Bhattacharjya, D. and Saikia, B.K., Coal-derived activated carbon for electrochemical energy storage: Status on supercapacitor, Li-ion battery, and Li–S battery applications, Energy Fuels, 35(22), 18285-18307(2021).

https://doi.org/10.1021/acs.energyfuels.1c02518

Chojnacka, K., Skrzypczak, D., Mikula, K., Witek-Krowiak, A., Izydorczyk, G., Paulina, B., Marek, K. and Kuligowski, K., Progress in sustainable technologies of leather waste valorization as solutions for the circular economy, J. Clean. Prod., 313, 127902(2021).

https://doi.org/10.1016/j.jclepro.2021.127902

Dehghani, S. A. R., Tharumalingam, E., Dusseault, M. B. and Fraser, R., Study of energy storage systems and environmental challenges of batteries, Renew. Sustain, Energy Rev., 104, 192-208(2019).

https://doi.org/10.1016/j.rser.2019.01.023

Dutta, A., Mitra, S., Basak, M. and Banerjee, T., A comprehensive review on batteries and supercapacitors: Development and challenges since their inception, Energy Storage, 5(1), e339(2023).

https://doi.org/10.1002/est2.339

Fagiolari, L., Sampò, M., Lamberti, A., Amici, J., Francia, C., Bodoardo, S. and Bella, F., Integrated energy conversion and storage devices: Interfacing solar cells, batteries, and supercapacitors, Energy Storage Mater., 51, 400-434(2022).

https://doi.org/10.1016/j.ensm.2022.06.051

Feng, X., Bai, Y., Liu, M., Li, Y., Yang, H., Wang, X. and Wu, C., Untangling the respective effects of heteroatom-doped carbon materials in batteries, supercapacitors, and the ORR to design high-performance materials, Energy Environ. Sci., 14(4), 2036-2089(2021).

https://doi.org/10.1039/D1EE00166C

Jain, A., Balasubramanian, R. and Srinivasan, M., Hydrothermal conversion of biomass waste to activated carbon with high porosity: A review, Chem. Eng. J., 283, 789-805(2016).

https://doi.org/10.1016/j.cej.2015.08.014

Jayaraman, T., Murthy, A. P., Elakkiya, V., Chandrasekaran, S., Nithyadharseni, P., Raja, A. S., Ravi, S., Mitty, R., Kuppusami, P., Madhavan, J., Ashokkumar, M. and Khan, Z., Recent development on carbon-based heterostructures for their applications in energy and environment: A review, J. Ind. Eng. Chem., 64, 16-59(2018).

https://doi.org/10.1016/j.jiec.2018.02.029

Kong, J., Yue, Q., Huang, L., Gao, Y., Sun, Y., Gao, B., Li, Q. and Wang, Y., Preparation, characterization, and evaluation of adsorptive properties of leather waste-based activated carbon via physical and chemical activation, Chem. Eng. J., 221, 62-71 (2013).

https://doi.org/10.1016/j.cej.2013.02.021

Li, W., Zhang, W., Xu, Y., Wang, G., Sui, W., Yuan, Z., Si, C. and Xu, T., Heteroatom-doped lignin-derived carbon materials for improved electrochemical performance: Synthesis, mechanism, and applications in advanced supercapacitors, Chem. Eng. J., 497, 154829(2024).

https://doi.org/10.1016/j.cej.2024.154829

Muralidharan, V., Palanivel, S. and Balaraman, M., Turning problem into possibility: A comprehensive review on leather solid waste intra-valorization attempts for leather processing, J. Clean. Prod., 367, 133021(2022).

https://doi.org/10.1016/j.jclepro.2022.133021

Paraknowitsch, J. P. and Thomas, A., Doping carbons beyond nitrogen: An overview of advanced heteroatom-doped carbons with boron, sulfur, and phosphorus for energy applications, Energy Environ. Sci., 6(10), 2839-2855(2013).

https://doi.org/10.1039/C3EE41444B

Silva, E. P., Fragal, V. H., Fragal, E. H., Sequinel, T., Gorup, L. F., Silva, R. and Muniz, E. C., Sustainable energy and waste management: How to transform plastic waste into carbon nanostructures for electrochemical supercapacitors, Waste Manag., 171, 71-85 (2023).

https://doi.org/10.1016/j.wasman.2023.08.028

Verma, S. K. and Sharma, P. C., Current trends in solid tannery waste management, Crit. Rev. Biotechnol., 43(5), 805-822(2023).

https://doi.org/10.1080/07388551.2022.2068996

Wang, X., Wang, Y., Yan, L., Wang, Q., Li, J., Zhong, X., Liu, Q., Li, Q., Cui, S. and Xie, G., From pollutant to high-performance supercapacitor: Semi-coking wastewater derived N–O–S self-doped porous carbon, Colloids Surf., A, 657, 130596(2023).

https://doi.org/10.1016/j.colsurfa.2022.130596

Wang, Y., Zhang, L., Hou, H., Xu, W., Duan, G., He, S., Liu, K. and Jiang, S., Recent progress in carbon-based materials for supercapacitor electrodes: A review, J. Mater. Sci., 56, 173-200(2021).

https://doi.org/10.1007/s10853-020-05157-6

Wood, K. N., O'Hayre, R. and Pylypenko, S., Recent progress on nitrogen/carbon structures designed for use in energy and sustainability applications, Energy Environ. Sci., 7(4), 1212-1249(2014).

https://doi.org/10.1039/C3EE44078H

Yu, F., Li, S., Chen, W., Wu, T. and Peng, C., Biomass-derived materials for electrochemical energy storage and conversion: Overview and perspectives, Energy Environ. Mater., 2(1), 55-67(2019).

https://doi.org/10.1002/eem2.12030

Zhang, S. S., Heteroatom-doped carbons: Synthesis, chemistry, and application in lithium/sulfur batteries, Inorg. Chem. Front., 2(12), 1059-1069(2015).

https://doi.org/10.1039/C5QI00153F

Zheng, B., Lin, X., Zhang, X., Wu, D. and Matyjaszewski, K., Emerging functional porous polymeric and carbonaceous materials for environmental treatment and energy storage, Adv. Funct. Mater., 30(41), 1907006(2020).

https://doi.org/10.1002/adfm.201907006

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