Open Access

Synthesis and Characterization Tetrakis(Hydrazine) Cadmium(II)Chloride Monohydrate Crystals

M. Dhandapani, srmvdhandapani@gamil.com
Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, TN, India.
V. Prabhua, Department of Science and Humanities, Sri Eshwar College of Engineering Kinathukadavu, Coimbatore, TN, India. P. Muthuraja, Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, TN, India. M. Sethuram, Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, TN, India. G. Amirthaganesan Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, TN, India.


J. Environ. Nanotechnol., Volume 2, No 4 (2013) pp. 11-14

https://doi.org/10.13074/jent.2013.12.132039

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Abstract

Single crystals of Tetrakis(hydrazine)cadmium(II) chloride monohydrate (TCCM) were synthesised and characterised. The crystals were synthesised by solvent evaporation technique at ambient temperature. The presence of different elements in the compound and their composition were confirmed by energy dispersive analysis of X-ray (EDAX) and elemental analysis (CHN). FTIR spectroscopy confirms the presence of functional groups and molecular structure has been confirmed by 1H NMR spectrum of the grown crystal. The sharp Bragg peaks from powder X-ray diffraction pattern shows crystalline nature of the compound. Thermal properties of TCCM were examined by thermogravimetry (TG), differential thermal analysis (DTA) and low temperature differential scanning calorimetry (DSC). Second-harmonic generation (SHG) measurement on the powder samples does not exhibit SHG efficiency.

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Reference


Balasubramanian, D., Murugakootha, P., Jayavel, R., Synthesis, growth and characterization of organic nonlinear optical bis-glycine maleate (BGM) single crystals, J.Cryst. Growth, 312, 1855-1859(2010).

http://http://dx.doi.org/10.1016/j.jcrysgro.2010.02.024

Cheetham, A. K., Solid State Chemistry Techniques, (Ed. A.K. Cheetham and P. Day), Oxford Science Publications, (1987).

Heaton, B. T., Jacob, C., Page, P., Transition metal complexes containing hydrazine and substituted hydrazines, Coord. Chem. Rev., 154, 193-229(1996).

http://dx.doi.org/10.1016/0010-8545(96)01285-4

Ravindra, R., Sridar, S., Khan, A. A., Separation studies of hydrazine from aqueous solutions by pervaporation, J. Polym. Sci., B: Polym. Phys., 37, 1969-1980(1999).

http://dx.doi.org/10.1002/(SICI)10990488(19990815)37:16<1969::AID-POLB2>3.0.CO;2-R

Serov, A., Kwak, C., Direct hydrazine fuel cells: A review, Applied Catalysis B. Environmental, 98, 1-9(2010).

http://http://dx.doi.org/10.1016/j.apcatb.2010.05.005 

Schaffer, D. J., Batsanov, A. S., Jensen, C. M., Takara, S., Syntheses and crystal structures of a series of palladium(II) and platinum(II) complexes bearing new hydrazine-based bisphosphinite ligands equipped with pyridyl arms, Polyhedron, 29, 1660-1666(2010) .

http://dx.doi.org/10.1016/j.poly.2010.02.011 

Vikram, L., Sivasankar, B.N., Spectral, thermal and X-ray studies on some new bis-hydrazine metal glyoxylates and bis-hydrazine mixed metal glyoxylates, Thermochim. Acta, 452, 20-27(2007).

http://http://dx.doi.org/10.1016/j.tca.2006.10.001

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