Structural, Morphological, and Photocatalytic Studies of Co-Doped MoO3 on SiO2: A Multifunctional Material for Environmental Remediation
J. Environ. Nanotechnol., Volume 13, No 4 (2024) pp. 326-331
Abstract
Molybdenum trioxide is a versatile material widely studied for its unique structural, electronic, and optical properties, making it suitable for applications in catalysis, photocatalysis, energy storage, and environmental remediation. In this study, the structural and functional properties of undoped and Co-doped MoO3 on SiO2 were systematically investigated through XRD, FESEM, TEM, UV-Vis, FTIR, EDS, and dye degradation experiments. The XRD analysis revealed the crystalline structure and lattice distortions induced by Co doping, while FESEM and TEM demonstrated the morphological evolution, including agglomeration and increased surface roughness. Optical studies using UV-Vis spectroscopy showed a bandgap narrowing upon doping, enhancing photocatalytic activity. The FTIR spectra highlighted shifts in vibrational modes, confirming structural modifications due to doping. The EDS analysis confirmed the successful incorporation of cobalt into the MoO3 matrix. The photocatalytic efficiency of 6% Co-doped MoO3 was evaluated using Isolan Black dye, with results showing significant degradation within 60 min. Based on the findings, the Co-doped MoO3 on SiO2 can be claimed as an efficient material for environmental and catalytic applications.
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Reference
Chen, J., Wang, L. and Huang, S., Enhanced photocatalytic performance of cobalt-doped molybdenum trioxide for organic pollutant degradation, Mater. Des., 215, 110091 (2022).
https://doi.org/10.1016/j.matdes.2022.110091
Elango, M., Kalpana, G., Varuna, J. and Sanjeevi, P., Influence of Mg concentration on structural, morphological and optical properties of nanoceria, Ceram. Int., 44(10), 11820-11827 (2018).
https://doi.org/10.1016/j.ceramint.2018.03.269
Li, M., Dong, Q. and Xu, F., High-resolution TEM analysis of transition metal-doped MoO₃: Structural insights and defect mechanisms, Mater. Des, 190, 107810 (2020).
https://doi.org/10.1016/j.matdes.2020.107810
Gunasekaran, S., Marnadu, R., Thangaraju, D., Chandrasekaran, J., Hegazy, H. H., Somaily, H. H., Durairajan, A., Valente, M.A., Elango, M., Vasudeva Reddy and Minnam Reddy, Development of n-MoO3@MoS2/p-Si heterostructure diode using pre-synthesized core@shell nanocomposite for efficient light harvesting detector application, Mater. Sci. Semicond. Process., 135, 106097 (2021).
https://doi.org/10.1016/j.mssp.2021.106097
Kumar, N., Irfan, G., Udayabhanu, G. and Nagaraju, Green synthesis of zinc oxide nanoparticles: Mechanical and microstructural characterization of aluminum nano composites, Mater. Today Proc., 38(5), 3116-3124 (2021).
https://doi.org/10.1016/j.matpr.2020.09.494
Kumar, S., Singh, A., Singh, R., Singh, S., Kumar, P. and Kumar, R., Facile h-MoO3 synthesis for NH3 gas sensing application at moderate operating temperature, Sens Actuators B Chem., 325, 128974 (2020).
https://doi.org/10.1016/j.snb.2020.128974
Rajesh, E. M., Shamili, K., Rajendran, R., Shankar, S. R. and Elango, M., Superparamagnetic Nanoparticles of Iron Oxide: Synthesis and Characterization, ASEM., 6 (3), 268-272 (2014).
https://doi.org/10.1166/asem.2014.1503
Tariq, N., Fatima, R., Rahman, A., Zulfqar, S., Warsi, M.F. and Shakir, I., Synthesis and characterization of MoO3/CoFe2O4 nanocomposite for photocatalytic applications. Ceram. Int., 46, 21596–21603 (2020).
https://doi.org/10.1016/j.ceramint.2020.05.264
Wang, J., Nie, X., Wang, W., Zhao, Z., Li, L. and Zhang, Z., Single-layer graphene-TiO2 nanotubes array heterojunction as photoanode to enhance the photoelectric of DSSCs, Optik, 242, 167245 (2021).
https://doi.org/10.1016/j.ijleo.2021.167245
Xu, H., Liu, C., Srinivasakannan, C., Chen, M., Wang, Q., Li, L. and Dai, Y., Hydrothermal synthesis of one-dimensional α-MoO3 nanomaterials and its unique sensing mechanism for ethanol, Arab. J. Chem., 15(9), 104083 (2022).
https://doi.org/10.1016/j.arabjc.2022.104083
Zhou, L., Mi, Q., Jin, Y. Tingting, Li. and Dongzhi, Z. Construction of MoO3/MoSe2 nanocomposite-based gas sensor for low detection limit trimethylamine sensing at room temperature, J. Mater. Sci: Mater Electron., 32, 17301–17310(2021).