Open Access

Application of Catalysts Used in Biodiesel Production - A Review

L. Nawin, Department of Chemical Engineering, National Institute of Technology Raipur, Raipur, CG, India Manash Kumar, Department of Chemical Engineering, National Institute of Technology Raipur, Raipur, CG, India Darshan , Department of Chemical Engineering, National Institute of Technology Raipur, Raipur, CG, India Chandrakant Thakur cthakur.che@nitrr.ac.in
Department of Chemical Engineering, National Institute of Technology Raipur, Raipur, CG, India


J. Environ. Nanotechnol., Volume 13, No 3 (2024) pp. 145-151

https://doi.org/10.13074/jent.2024.09.242716

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Abstract

Biodiesel stands as a promising alternative to traditional fossil fuels for transportation, boasting renewability, biodegradability, and environmental friendliness. However, the efficiency of biodiesel production hinges on the catalytic processes that expedite the crucial transesterification reaction between triglycerides and alcohols. The choice of catalyst becomes a multifaceted decision, influenced by factors such as feedstock quality, specific reaction conditions, and the environmental footprint associated with the catalyst itself. This comprehensive paper deals the current state of catalysts employed in biodiesel production, offering readers a nuanced understanding of the subject. The catalyst landscape is explored through an intricate analysis of various types, encompassing homogeneous, heterogeneous, enzymatic, nano, and bio-derived catalysts. A critical component of the paper is the exploration of recent advancements in catalyst synthesis techniques. This includes an assessment of the performance of these novel catalysts, elucidating their potential contributions to enhancing the biodiesel production process. By offering insights into the future prospects of these catalysts within the context of biodiesel production, the paper contributes to the evolving discourse on sustainable energy sources. In pursuit of its overarching goal, the paper aspires to furnish readers with more than just an up-to-date overview; it aims to provide a thorough examination of the prevailing trends and challenges in the realm of catalyst utilization for biodiesel production. As the world seeks greener alternatives, this paper offers valuable insights that extend beyond the present, fostering a deeper understanding of the dynamics shaping the future of biodiesel production and sustainable transportation.

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Reference


Adewale, P., Dumont, M. J., and Ngadi, M., Enzyme-catalyzed synthesis and kinetics of ultrasonic-assisted biodiesel production from waste tallow, Ultrason Sonochem, 27, 1–9 (2015).

https://doi.org/10.1016/j.ultsonch.2015.04.032

Agarwal, A. K., Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines, Prog. Energy Combust. Sci., 33 (3), 233–271 (2007).

https://doi.org/10.1016/j.pecs.2006.08.003

Agarwal, M., Chauhan, G., Chaurasia, S.P., and Singh, K., Study of catalytic behavior of KOH as homogeneous and heterogeneous catalyst for biodiesel production, J Taiwan Inst Chem Eng, 43 (1), 89–94 (2012).

https://doi.org/10.1016/j.jtice.2011.06.003

Alamu, O.J., Waheed, M.A., and Jekayinfa, S.O., Effect of ethanol–palm kernel oil ratio on alkali-catalyzed biodiesel yield, Fuel, 87 (8–9), 1529–1533 (2008).

https://doi.org/10.1016/j.fuel.2007.08.011

Alptekin, E., and Canakci, M., Optimization of transesterification for methyl ester production from chicken fat, Fuel, 90 (8), 2630–2638 (2011).

https://doi.org/10.1016/j.fuel.2011.03.042

Aniokete, T.C., Sadare, O.O., and Daramola, M.O., Prospects of biodiesel production from waste animal fats,. In: Waste and Biodiesel. Elsevier, 17–44 (2022).

https://doi.org/10.1016/B978-0-12-823958-2.00002-1

Atadashi, I.M., Aroua, M.K., Abdul Aziz, A.R., and Sulaiman, N.M.N., The effects of catalysts in biodiesel production: A review, Journal of Industrial and Engineering Chemistry, 19 (1), 14–26 (2013).

https://doi.org/10.1016/j.jiec.2012.07.009

Avhad, M. R., Gangurde, L. S., Sánchez, M., Bouaid, A., Aracil, J., Martínez, M., and Marchetti, J.M., Enhancing Biodiesel Production Using Green Glycerol-Enriched Calcium Oxide Catalyst: An Optimization Study, Catal Letters, 148 (4), 1169–1180 (2018).

https://doi.org/10.1007/s10562-018-2312-9

Awogbemi, O., Kallon, D.V. Von., Aigbodion, V.S., and Panda, S., Advances in biotechnological applications of waste cooking oil, Case Studies in Chemical and Environmental Engineering, 4 100158 (2021).

https://doi.org/10.1016/j.cscee.2021.100158

Benti, N.E., Aneseyee, A.B., Geffe, C.A., Woldegiyorgis, T.A., Gurmesa, G.S., Bibiso, M., Asfaw, A.A., Milki, A.W., and Mekonnen, Y.S., Biodiesel production in Ethiopia: Current status and future prospects, Sci Afr, 19 e01531 (2023).

https://doi.org/10.1016/j.sciaf.2022.e01531

da Costa Evangelista, J.P., Gondim, A.D., Souza, L. Di., and Araujo, A.S., Alumina-supported potassium compounds as heterogeneous catalysts for biodiesel production: A review, Renewable and Sustainable Energy Reviews, 59 887–894 (2016).

https://doi.org/10.1016/j.rser.2016.01.061

Dharma, S., Ong, H.C., Masjuki, H.H., Sebayang, A.H., and Silitonga, A.S., An overview of engine durability and compatibility using biodiesel–bioethanol–diesel blends in compression-ignition engines, Energy Convers Manag, 128 66–81 (2016).

https://doi.org/10.1016/j.enconman.2016.08.072

Dossin, T.F., Reyniers, M.-F., Berger, R.J., and Marin, G.B., Simulation of heterogeneously MgO-catalyzed transesterification for fine-chemical and biodiesel industrial production, Appl Catal B, 67 (1–2), 136–148 (2006).

https://doi.org/10.1016/j.apcatb.2006.04.008

Du, E., Cai, L., Huang, K., Tang, H., Xu, X., and Tao, R., Reducing viscosity to promote biodiesel for energy security and improve combustion efficiency, Fuel, 211 194–196 (2018).

https://doi.org/10.1016/j.fuel.2017.09.055

Ehsan, M., and Chowdhury, M.T.H., Production of Biodiesel Using Alkaline Based Catalysts From Waste Cooking Oil: A Case Study, Procedia Eng, 105 638–645 (2015).

https://doi.org/10.1016/j.proeng.2015.05.042

Ejikeme, P. M., Anyaogu, I. D., Ejikeme, C. L., Nwafor, N. P., Egbuonu, C. A. C., Ukogu, K., Ibemesi, J. A., Catalysis in Biodiesel Production by Transesterification Processes-An Insight. E-J. Chem, 7, 689051 (2010).

https://doi.org/10.1155/2010/689051

Ferreira Mota, G., Germano de Sousa, I., Luiz Barros de Oliveira, A., Luthierre Gama Cavalcante, A., da Silva Moreira, K., Thálysson Tavares Cavalcante, F., Erick da Silva Souza, J., Rafael de Aguiar Falcão, Í., Guimarães Rocha, T., Bussons Rodrigues Valério, R., Cristina Freitas de Carvalho, S., Simão Neto, F., de França Serpa, J., Karolinny Chaves de Lima, R., Cristiane Martins de Souza, M., and dos Santos, J.C.S., Biodiesel production from microalgae using lipase-based catalysts: Current challenges and prospects, Algal Res, 62 102616 (2022).

https://doi.org/10.1016/j.algal.2021.102616

Gadore, V., Mishra, S. R., Yadav, N., Yadav, G. and Ahmaruzzaman, Md., Metal oxide-based heterogeneous catalysts for biodiesel production, Next Sustainability, 2, 100012 (2023).

https://doi.org/10.1016/j.nxsust.2023.100012

Ghedini, E., Taghavi, S., Menegazzo, F., and Signoretto, M., A Review on the Efficient Catalysts for Algae Transesterification to Biodiesel, Sustainability, 13 (18), 10479 (2021).

https://doi.org/10.3390/su131810479

Günay, M.E., Türker, L., and Tapan, N.A., Significant parameters and technological advancements in biodiesel production systems, Fuel, 250 27–41 (2019).

https://doi.org/10.1016/j.fuel.2019.03.147

Gungormus, E., Seker, E., and Alsoy Altinkaya, S., Antifouling Polydopamine-Modified Poly (ether sulfone) Membrane Immobilized With Alumina-Calcium Oxide Catalyst For Continuous Biodiesel Production, Fuel, 349 128685 (2023).

https://doi.org/10.1016/j.fuel.2023.128685

Guo, J., Wang, Y., and Fang, Z., Covalent immobilization of lipase on magnetic biochar for one-pot production of biodiesel from high acid value oil, Bioresour Technol, 394 130237 (2024).

https://doi.org/10.1016/j.biortech.2023.130237

Gupta, J.G., and Agarwal, A.K., Engine durability and lubricating oil tribology study of a biodiesel fuelled common rail direct injection medium-duty transportation diesel engine, Wear, 486–487 204104 (2021).

https://doi.org/10.1016/j.wear.2021.204104

Gupta, A.R., and Rathod, V.K., Waste cooking oil and waste chicken eggshells derived solid base catalyst for the biodiesel production: Optimization and kinetics, Waste Management, 79 169–178 (2018).

https://doi.org/10.1016/j.wasman.2018.07.022

Huang, Z., ChenYang, Y., Wang, X., Cai, R., and Han, B., Biodiesel synthesis through soybean oil transesterification using choline-based amino acid ionic liquids as catalysts, Ind Crops Prod, 208 117869 (2024).

https://doi.org/10.1016/j.indcrop.2023.117869

Karmakar, B., Datta, A., Mishra, J.R., Rokhum, S.L., and Halder, G., Catalysed biodiesel synthesis from non-edible Nagkesar and Rubber seed oil blends using C1-C3 alcohol mixtures: Process optimization, kinetics and thermodynamics, Bioresour Technol Rep, 24 101618 (2023).

https://doi.org/10.1016/j.biteb.2023.101618

Khoobbakht, G., Karimi, M., and Kheiralipour, K., Effects of biodiesel-ethanol-diesel blends on the performance indicators of a diesel engine: A study by response surface modeling, Appl Therm Eng, 148 1385–1394 (2019).

https://doi.org/10.1016/j.applthermaleng.2018.08.025

Kosuru S. M. Y., Delhiwala Y., Koorla P. B., and Mekala M., A review on the biodiesel production: Selection of catalyst, Pre-treatment, Post treatment methods, Green Technol and Sustain, 2(1), 100061, (2024).

https://doi.org/10.1016/j.grets.2023.100061

Lani, N.S., Ngadi, N., Mohammed Inuwa, I., Anako Opotu, L., Zakaria, Z.Y., and Haron, S., A cleaner approach with magnetically assisted reactor setup over CaO-zeolite/Fe3O4 catalyst in biodiesel production: Evaluation of catalytic performance, reusability and life cycle assessment studies, J Clean Prod, 419 138329 (2023).

https://doi.org/10.1016/j.jclepro.2023.138329

Li, F., Hülsey, M.J., Yan, N., Dai, Y., and Wang, C.-H., Co-transesterification of waste cooking oil, algal oil and dimethyl carbonate over sustainable nanoparticle catalysts, Chemical Engineering Journal, 405 127036 (2021).

https://doi.org/10.1016/j.cej.2020.127036

Li, Y., Wen, Y., Chen, B., Fu, X., and Wu, Y., The dilemma and potential development of biodiesel in China - In view of production capacity and policy, Energy for Sustainable Development, 75 60–71 (2023).

https://doi.org/10.1016/j.esd.2023.05.005

Manurung, R., Hasibuan, R., and Siregar, A.G.A., Preparation and characterization of lithium, sodium, and potassium silicate from palm leaf as a potential solid base catalyst in developed biodiesel production, Case Studies in Chemical and Environmental Engineering, 9 100543 (2024).

https://doi.org/10.1016/j.cscee.2023.100543

Marchetti, J.M., The effect of economic variables over a biodiesel production plant, Energy Convers Manag, 52 (10), 3227–3233 (2011).

https://doi.org/10.1016/j.enconman.2011.05.008

Marwaha, A., and Subramanian, K.A., Performance enhancement and emissions reduction of ethanol‐fueled spark ignition engine with hydrogen, Biofuels, Bioproducts and Biorefining, 18 (3), 701–719 (2024).

https://doi.org/10.1002/bbb.2539

Moazeni, F., Chen, Y.-C., and Zhang, G., Enzymatic transesterification for biodiesel production from used cooking oil, a review, J Clean Prod, 216 117–128 (2019).

https://doi.org/10.1016/j.jclepro.2019.01.181

Nuhma, M.J., Alias, H., Tahir, M., and Jazie, A.A., Microalgae biomass conversion into biofuel using modified HZSM-5 zeolite catalyst: A review, Mater Today Proc, 42 2308–2313 (2021).

https://doi.org/10.1016/j.matpr.2020.12.320

Pirouzfar, V., Sakhaeinia, H., and Su, C.-H., Power generation using produced biodiesel from palm oil with GTG, STG and combined cycles; process simulation with economic consideration, Fuel, 314 123084 (2022).

https://doi.org/10.1016/j.fuel.2021.123084

Rahman, A., Dargusch, P., and Wadley, D., The political economy of oil supply in Indonesia and the implications for renewable energy development, Renewable and Sustainable Energy Reviews, 144 111027 (2021).

https://doi.org/10.1016/j.rser.2021.111027

Simhadri, K., Rao, P.S., and Paswan, M., Improving the combustion and emission performance of a diesel engine with TiO2 nanoparticle blended Mahua biodiesel at different injection pressures, International Journal of Thermofluids, 21 100563 (2024).

https://doi.org/10.1016/j.ijft.2024.100563

Singh, V., Hameed, B.H., and Sharma, Y.C., Economically viable production of biodiesel from a rural feedstock from eastern India, P. pinnata oil using a recyclable laboratory synthesized heterogeneous catalyst, Energy Convers Manag, 122 52–62 (2016).

https://doi.org/10.1016/j.enconman.2016.05.030

Singh, V., and Sharma, Y.C., Low cost guinea fowl bone derived recyclable heterogeneous catalyst for microwave assisted transesterification of Annona squamosa L. Seed oil, Energy Convers Manag, 138 627–637 (2017).

https://doi.org/10.1016/j.enconman.2017.02.037

Vicente, G., Martı́nez, M., and Aracil, J., Integrated biodiesel production: a comparison of different homogeneous catalysts systems, Bioresour Technol, 92 (3), 297–305 (2004).

https://doi.org/10.1016/j.biortech.2003.08.014

Yaakob, Z., Mohammad, M., Alherbawi, M., Alam, Z., and Sopian, K., Overview of the production of biodiesel from Waste cooking oil, Renewable and Sustainable Energy Reviews, 18 184–193 (2013).

https://doi.org/10.1016/j.rser.2012.10.016

Yusuff, A.S., Gbadamosi, A.O., and Atray, N., Development of a zeolite supported CaO derived from chicken eggshell as active base catalyst for used cooking oil biodiesel production, Renew Energy, 197 1151–1162 (2022).

https://doi.org/10.1016/j.renene.2022.08.032

Zhang, Y., and Sun, S., A review on biodiesel production using basic ionic liquids as catalysts, Ind Crops Prod, 202 117099 (2023).

https://doi.org/10.1016/j.indcrop.2023.117099

Zheng, B., Chen, J.-Y., Song, Z., Mao, E., Zhou, Q., Luo, Z., and Liu, K., Prediction and optimization of emission in an agricultural harvest engine with biodiesel-diesel blends by a method of ANN and CMA-ES, Comput Electron Agric, 197 106903 (2022).

https://doi.org/10.1016/j.compag.2022.106903

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