Open Access

Development and Characterization of Acrylonitrile (NBR)/ Styrene-Butadiene (SBR) Blends Reinforced with Halloysite Nanotubes

Ambika Joshi, ambikajoshi123@gmail.com
Department of Chemical Engineering, National Institute of Technology, Raipur, CG, India
A. B. Soni, Central Institute of Petrochemicals Engineering & Technology, Raipur, CG, India Alok Sahu Central Institute of Petrochemicals Engineering & Technology, Raipur, CG, India


J. Environ. Nanotechnol., Volume 13, No 2 (2024) pp. 391-396

https://doi.org/10.13074/jent.2024.06.242610

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Abstract

Elastomeric blends based on Nitrile (NBR) and Styrene butadiene rubber (SBR) are compatibilized by 6% Chlorinated polyethylene (CPE) and further reinforced with Halloysite nanotubes in various % loading (1%, 2%, 3% & 4%) in a two roll mill mixer for preparation of nanocomposites with enhanced properties. Further to enhance the effect of nanofillers and to increase the interaction of nanofiller with rubber matrix, HNT’s were functionalized by 30% H2SO4 by adopting the modification process. Tensile strength, elongation at break, modulas of elasticity, tear strength, hardness & thermal stability was studied. The result revealed that the blends reinforced with 3% modified HNT’s showed better results as compared to blends with unmodified HNT’s.

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Reference


Akshay, K., Arjun, M., Govind, S. S., Hrithwik, V., Akhil, S., Rahulan, N., Mechanical behavior of silicon carbide filled SBR/NBR blends, Mater. Today Proc. 42, 1432–1436 (2021).

https://doi.org/10.1016/j.matpr.2021.01.234

Anand, N. A. G., Rajesh Babu, R. Vasanthakumari, Studies on Halloysite Nanotubes(HNT) Natural Rubber Nanocomposites for Mechanical Thermal and Wear Properties, Int J Eng Res.

https://doi.org/10.17577/IJERTV5IS030167

George, S. C., Ninan, K. N., Groeninckx, G., Thomas, S., Styrene-butadiene rubber/natural rubber blends: Morphology, transport behavior, and dynamic mechanical and mechanical properties, J. Appl. Polym. Sci. 78(6), 1280–1303 (2000).

https://doi.org/10.1002/1097-4628(20001107)78:6<1280::AID-APP150>3.0.CO;2-S

Paran, S. M. R., Naderi, G., Mirzaee, M., Ghoreishy, M. H. R., Włoch, M., Esmaeili, A., Abida, O., Saeb, M. R., Microstructure–properties relationship in ethylene-propylene diene monomer (EPDM)/nitrile butadiene rubber (NBR)/halloysite nanotubes (HNTs) nanocomposites, Polym. Bull. 81(1), 755–772 (2024).

https://doi.org/10.1007/s00289-023-04723-7

Ramesan, M. T., Alex, R., Compatibilization of SBR/NBR blends using chemically modified styrene‐ co ‐butadiene rubber Part 2. Effect of compatibilizer loading, Polym. Int. 50(12), 1298–1308 (2001).

https://doi.org/10.1002/pi.775

Rooj, S., Das, A., Thakur, V., Mahaling, R. N., Bhowmick, A. K., Heinrich, G., Preparation and properties of natural nanocomposites based on natural rubber and naturally occurring halloysite nanotubes, Mater. Des. 31(4), 2151–2156 (2010).

https://doi.org/10.1016/j.matdes.2009.11.009

Yeswin, C., Vamsi, D. B. S., Vijay, B. N., Naveen, I., Reddy, P. S. P., Rahulan, N., Physical properties of nano Al2O3 reinforced NBR/SBR blends, Mater. Today Proc. 52, 2273–2278 (2022).

https://doi.org/10.1016/j.matpr.2021.08.241

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