Open Access

Synergistic Performance of Pectin with Monoethylene glycol as Environment Friendly and Sustainable Hydrate Inhibitor

Ankur Singh, Centre for Development of Biomaterials, Sharda University, Greater Noida, UP, India
Mechanical Engineering Department, SSET, Sharda University, Greater Noida, UP, India
Sujoy Kumar Dey, dey.sujoykumar@gmail.com
Mechanical Engineering Department, SSET, Sharda University, Greater Noida, UP, India
Akanksha Mishra, Mechanical Engineering Department, SSET, Sharda University, Greater Noida, UP, India Ajay Suri Department of Petroleum Engineering, IIT (ISM), Dhanbad, JH, India


J. Environ. Nanotechnol., Volume 13, No 2 (2024) pp. 331-338

https://doi.org/10.13074/jent.2024.06.241525

PDF


Abstract

This research explores the capability of pectin as a hydrate inhibitor, along with its potential synergy with monoethylene glycol (MEG). The inhibitory performance was evaluated by measuring the induction time (IT) required for hydrate formation under various concentrations (0.25 wt%, 0.5 wt%, and 1 wt%), employing methane gas at a pressure of 7.6 MPa with hydrate equilibrium temperature at 10.45 ℃. The cooling process was meticulously maintained at a consistent rate of 1℃ per hour below the hydrate equilibrium temperature throughout the experiment. Results revealed that while pectin exhibited slightly lower performance compared to commercial Kinetic Hydrate Inhibitors (KHIs), it demonstrates promising potential as a viable alternative to traditional non-biodegradable and unsustainable KHIs. However, when blended with MEG, its performance increased rapidly. This is particularly significant for the smooth operation of the oil and gas industry offshore, where environmental concerns take precedence. The ability of pectin and MEG combination to effectively inhibit hydrate formation, combined with their biodegradable properties, positions it as an attractive candidate for future research in the field of deep-sea hydrate risk management.

Full Text

Reference


Anderson, F. E. and Prausnitz, J. M., Inhibition of gas hydrates by methanol, AIChE Journal, 32(8), 1321–1333 (1986).

https://doi.org/10.1002/aic.690320810

Carver, T. J., Drew, M. G .B. and Rodger, P. M., Inhibition of crystal growth in methane hydrate, Faraday Trans., 91(19), 3449 (1995).

https://doi.org/10.1039/ft9959103449

Chin, Y. D. and Srivastava, A., Advances in LDHIs and Applications, Houston, Texas, USA, D041S052R001 (2018).

Colin D., M., Industrial Pectins: Sources, Production and Applications, Carbohydr. Polym., 12(1), 79–99 (1990).

Dorota, G., Długosz, M., Lesław, J., Kazunori, T., Jun-ichi, A., Kaori, S., Yoshihiro, S., Morimura, S., Kenji, K. and Pornsak, S., Chemistry of Pectin and Its Pharmaceutical Uses : A Review, Silpakorn University Open Journal Systems, 3(4), 206–228 (2003).

Eubeler, J. P., Bernhard, M. and Knepper, T. P., Environmental biodegradation of synthetic polymers II. Biodegradation of different polymer groups, TrAC, Trends Anal. Chem., 29(1), 84–100 (2010).

https://doi.org/10.1016/j.trac.2009.09.005

Eubeler, J. P. Zok, S. Bernhard, M. and Knepper, T. P., Environmental biodegradation of synthetic polymers I. Test methodologies and procedures, TrAC, Trends Anal. Chem., 28(9), 1057–1072 (2009).

https://doi.org/10.1016/j.trac.2009.06.007

Exon, J. H., A Review of the Toxicology of Acrylamide, J. Toxicol. Environ. Health Part B, 9(5), 397–412 (2006).

https://doi.org/10.1080/10937400600681430

Farhadian, A., Varfolomeev, M. A., Kudbanov, A. and Gallyamova, S. R., A new class of promising biodegradable kinetic/anti-agglomerant methane hydrate inhibitors based on castor oil, Chem. Eng. Sci., 206 507–517 (2019).

https://doi.org/10.1016/j.ces.2019.05.055

Frostman, L. M., Thieu, V., Crosby, D. L. and Downs, H. H., Low-Dosage Hydrate Inhibitors (LDHIs): Reducing Costs in Existing Systems and Designing for the Future, All Days, In: All Days, SPE, Houston, Texas, SPE-80269-MS (2003).

Fu, B. Neff, S. Mathur, A. and Bakeev, K., Application of Low-Dosage Hydrate Inhibitors in Deepwater Operations, SPE Prod. Facil., 17(03), 133–137 (2002).

https://doi.org/10.2118/78823-PA

Fu, S. B., Cenegy, L. M. and Neff, C. S., A Summary of Successful Field Applications of A Kinetic Hydrate Inhibitor, All Days, In: All Days, SPE, Houston, Texas, SPE-65022-MS (2001).

Gad, S. C., Robinson, K., Serota, D. G. and Colpean, B. R., Developmental toxicity studies of caprolactam in the rat and rabbit, J. Appl. Toxicol., 7(5), 317–326 (1987).

https://doi.org/10.1002/jat.2550070506

Glénat, P., Peytavy, J. L., Holland, J. N. and Grainger, M., South-Pars Phases 2 and 3: The Kinetic Hydrate Inhibitor (KHI) Experience Applied at Field Start-up, All Days, In: All Days, SPE, Abu Dhabi, United Arab Emirates, SPE-88751-MS (2004).

Kelland, M. A., A Review of Kinetic Hydrate Inhibitors from an Environmental Perspective, Energy Fuels, 32(12), 12001–12012 (2018).

https://doi.org/10.1021/acs.energyfuels.8b03363

Lin, H., Wolf, T., Wurm, F. R. and Kelland, M. A., Poly(alkyl ethylene phosphonate)s: A New Class of Non-amide Kinetic Hydrate Inhibitor Polymers, Energy Fuels, 31(4), 3843–3848 (2017).

https://doi.org/10.1021/acs.energyfuels.7b00019

MacDonald, A. W. R., Petrie, M., Wylde, J. J., Chalmers, A. J. and Arjmandi, M., Field Application of Combined Kinetic Hydrate and Corrosion Inhibitors in the Southern North Sea: Case Studies, All Days, In: All Days, SPE, Calgary, Alberta, Canada, SPE-99388-MS (2006).

Mahmoud, N. Tohidi, B. and Chapoy, A., An Evaluation of Risk of Hydrate Formation at the Top of a PipelineOil and Gas Facilities, 68 67–72 (2014).

O’Reilly, R. Ieong, N. S. Chua, P. C. and Kelland, M. A., Crystal growth inhibition of tetrahydrofuran hydrate with poly(N-vinyl piperidone) and other poly(N-vinyl lactam) homopolymers, Chem. Eng. Sci., 66(24), 6555–6560 (2011).

https://doi.org/10.1016/j.ces.2011.09.010

Pereira, D. G. M. Vieira, J. M., Vicente, A. A. and Cruz, R. M. S., Development and Characterization of Pectin Films with Salicornia ramosissima: Biodegradation in Soil and Seawater, Polym., 13(16), 2632 (2021).

https://doi.org/10.3390/polym13162632

Rudolf, K., Binding of Toxic Cations to Pectin, Its Oligomeric Fragments and Plant Tissues, Carbohydr. Polym., 2(4), 273–275 (1982).

Singh, A. and Suri, A., A review on gas hydrates and kinetic hydrate inhibitors based on acrylamides, J. Nat. Gas Sci. Eng., 83 103539 (2020).

https://doi.org/10.1016/j.jngse.2020.103539

Singh, A. and Suri, A., Review of Kinetic Hydrate Inhibitors Based on Cyclic Amides and Effect of Various Synergists, Energy Fuels, 35(19), 15301–15338 (2021).

https://doi.org/10.1021/acs.energyfuels.1c02180

Singh, A. and Suri, A., Enhanced Hydrate Inhibition by Plant-Based Polysaccharides as Synergists with Kinetic Hydrate Inhibitors, Energy Fuels, 36(13), 6974–6988 (2022).

https://doi.org/10.1021/acs.energyfuels.2c01062

Singh, A. and Suri, A., Synergistic Kinetic Hydrate Inhibition of Pectin, PVP, and PVCap with Monoethylene Glycol, Energy Fuels, 37(6), 4524–4543 (2023).

https://doi.org/10.1021/acs.energyfuels.3c00065

Singh, A. Suri, A. and Chandravanshi, D., Kinetic Hydrate Inhibition by Lambda-Carrageenan and Its Synergistic Compositions with Ethylene Glycol, 4-Methyl-1-Pentanol, Polyvinylpyrrolidone, and Polyvinylcaprolactam, Energy Fuels, 37(13), 9368–9383 (2023a).

https://doi.org/10.1021/acs.energyfuels.3c00674

Singh, A. Suri, A. and Date, A., Synergistic Hydrate Inhibition by Bovine Serum Albumin With Kinetic Hydrate Inhibitors, Day 1 Wed, March 15, 2023, In: Day 1 Wed, March 15, 2023, SPE, Calgary, Alberta, Canada, D011S005R002 (2023b).

Swanson, T. A. Petrie, M. and Sifferman, T. R., The Successful Use of Both Kinetic Hydrate and Paraffin Inhibitors Together in a Deepwater Pipeline with a High Water Cut in the Gulf of Mexico, All Days, In: All Days, SPE, The Woodlands, Texas, SPE-93158-MS (2005).

Wang, F. Zhang, J. N. and Li, C. X., Study on Hydrate Inhibitor to Prevent Freeze-Plugging of Gas-Condensate Well, AMR, 868 737–741 (2013).

https://doi.org/10.4028/www.scientific.net/AMR.868.737

Wu, M. Wang, S. and Liu, H., A Study on Inhibitors for the Prevention of Hydrate Formation in Gas Transmission Pipeline, J. Nat. Gas Chem., 16(1), 81–85 (2007).

https://doi.org/10.1016/S1003-9953(07)60031-0

Xu, S., Fan, S., Fang, S., Lang, X., Wang, Y. and Chen, J., Pectin as an Extraordinary Natural Kinetic Hydrate Inhibitor, Sci Rep, 6(1), 23220 (2016).

https://doi.org/10.1038/srep23220

Yaqub, S. Lal, B. Shariff, A. B.M. and Mellon, N. Bt., Unraveling the effect of sub-cooling temperatures on the kinetic performance of biopolymers for methane hydrate, J. Nat. Gas Sci. Eng., 65 68–81 (2019).

https://doi.org/10.1016/j.jngse.2019.03.002

Yaqub, S. Murtaza, M. and Lal, B., Towards a fundamental understanding of biopolymers and their role in gas hydrates: A review, J. Nat. Gas Sci. Eng., 91 103892 (2021).

https://doi.org/10.1016/j.jngse.2021.103892

Contact Us

  • No. 53, II Street,
    Rock Mount City, Erode,
    TN, India - 638112
  • editorjent@gmail.com
  • +91 94422 64501

Powered by

Powered by OJS