Open Access

Selective Fluorescence Chemosensor for Al3+ based on Antipyrine with Furfural Attached Allyl System

P. Rajasingh, sprajasingh@gmail.com
Department of Chemistry, Chikkanna Government Arts College, Tirupur, TN, India
P. Banumathi, Department of Chemistry, Chikkanna Government Arts College, Tirupur, TN, India G. Tamil Selvan, Department of Chemistry, KITS, Coimbatore, TN, India P. Mosae Selvakumar Science and Math Program, Asian University for Women, Chittagong, Bangladesh


J. Environ. Nanotechnol., Volume 10, No 2 (2021) pp. 01-05

https://doi.org/10.13074/jent.2021.06.212435

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Abstract

By incorporating Furfural-Antipyrine as coordinate sites into the fragment of receptor Furfural Baylis Hillman-Antipyrine (FBH-AP), it can be used as an artificial chemosensor for selective recognition of transition metals. The strong fluorescence emission at 388 nm of the receptor FBH-AP is effectively and selectively quenched by Al3+. A 1:1 complex formed between the FBH-AP and Al3+ is determined by the Jobs plot and their common interferent ions do not show any interference with Al3+. It is anticipated that the antipyrine could be a good candidate probe and has potential application for Al3+ determination.

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